Zero-birefringence optical polymers

Akihiro Tagaya, Hisanori Ohkita, Tomoaki Harada, Kayoko Ishibashi, Yasuhiro Koike

Research output: Contribution to journalArticle

84 Citations (Scopus)

Abstract

Here we demonstrate, for the first time, that it is possible to synthesize a polymer that exhibits no orientational birefringence and no photoelastic birefringence using two methods. In these methods, the contributions of monomers and an anisotropic dopant to orientational birefringence and photoelastic birefringence are analyzed experimentally, after which the composition of a ternary copolymer or a binary copolymer including the dopant is adjusted, based on the results, to compensate for both types of birefringence. By the methods and fine adjustment of the composition, we synthesized poly(methyl methacrylate (MMA)/2,2,2-trifluoroethyl methacrylate (3FMA)/ benzyl methacrylate = 52.0/42.0/6.0(w/w/w)) and poly(MMA/3FMA = 85.0/15.0(w/w)) containing 2.8 wt % of trans-stilbene that exhibited close to zero birefringence.

Original languageEnglish
Pages (from-to)3019-3023
Number of pages5
JournalMacromolecules
Volume39
Issue number8
DOIs
Publication statusPublished - 2006 Apr 18

ASJC Scopus subject areas

  • Organic Chemistry
  • Polymers and Plastics
  • Inorganic Chemistry
  • Materials Chemistry

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  • Cite this

    Tagaya, A., Ohkita, H., Harada, T., Ishibashi, K., & Koike, Y. (2006). Zero-birefringence optical polymers. Macromolecules, 39(8), 3019-3023. https://doi.org/10.1021/ma0527000