Zero–birefringence polymer by the anisotropic molecule dope method

Akihiro Tagaya, Shuichi Iwata, Eriko Kawanami, Hisashi Tsukahara, Yasuhiro Koike

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40 Citations (Scopus)

Abstract

We propose using the anisotropic molecule dope method for synthesizing a zero-birefringence polymer that showed no orientational birefringence at any orientation degree of polymer chains. In this method a rodlike molecule with polarizability anisotropy was chosen to compensate orientational birefringence. The zero-birefringence polymer was synthesized by doping of 3-wt.% trans-stilbene as an anisotropic molecule into poly (methyl methacrylate). The zero-birefringence at the 590-nm wavelength in the drawn film and the injection-molded plate made from the zero-birefringence polymer was confirmed by the rotating parallel nicols method. Furthermore, high transparency (37.2 dBykm) of the zerobirefringence polymer at the 633-nm wavelength was confirmed by the light-scattering measurement.

Original languageEnglish
Pages (from-to)3677-3683
Number of pages7
JournalApplied Optics
Volume40
Issue number22
DOIs
Publication statusPublished - 2001 Aug 1

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ASJC Scopus subject areas

  • Atomic and Molecular Physics, and Optics
  • Engineering (miscellaneous)
  • Electrical and Electronic Engineering

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