河内 卓彌

研究成果

年別の研究成果 1999 2009 2010 2011 2013 2017 2019 2020 2021 2021

• 4154 被引用数
• 35 h-index
• 80 Article
• 5 Review article
• 2 Paper
• 2 Comment/debate

年別の研究成果

年別の研究成果

検索結果

• Article

  2:1 versus 1:1 Coupling of Alkylacetylenes with Secondary Amines: Selectivity Switching in 8-Quinolinolato Rhodium Catalysis

  Morimoto, Y., Hamada, M., Takano, S., Mochizuki, K., Kochi, T. & Kakiuchi, F., 2021 5月 21, In: Organic Letters. 23, 10, p. 3803-3808 6 p.

  研究成果: Article › 査読

  • Rhodium 100%
  • rhodium 73%
  • Hydroamination 72%
  • Catalysis 67%
  • amines 65%
  3 被引用数 (Scopus)

• Alternating copolymerization of vinyl acetate with carbon monoxide

  Kochi, T., Nakamura, A., Ida, H. & Nozaki, K., 2007 6月 27, In: Journal of the American Chemical Society. 129, 25, p. 7770-7771 2 p.

  研究成果: Article › 査読

  • vinyl acetate 100%
  • Copolymerization 89%
  • Copolymers 73%
  • Monomers 72%
  • Carbon monoxide 67%
  67 被引用数 (Scopus)

• Anti-Markovnikov Addition of Anilines to Aliphatic Terminal Alkynes Catalyzed by an 8-Quinolinolato Rhodium Complex

  Morimoto, Y., Kochi, T. & Kakiuchi, F., 2021 10月, In: Helvetica Chimica Acta. 104, 10, e2100125.

  研究成果: Article › 査読

  • 1,1,3,3-tetramethylguanidine 100%
  • Aniline Compounds 75%
  • Rhodium 73%
  • phosphine 70%
  • alkynes 68%

• Asymmetric Synthesis of Amines with tert-Butanesulfinamide and Its Application

  Kochi, T., Mukade, T. & Ellman, J. A., 2004 2月, In: Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry. 62, 2, p. 128-139 12 p.

  研究成果: Article › 査読

  Open Access

  • Amine 100%
  • Imine 55%
  • Application 48%
  • Ketimine 40%
  • Aldimine 39%
  10 被引用数 (Scopus)

• Asymmetric synthesis of syn- and anti-1,3-amino alcohols

  Kochi, T., Tang, T. P. & Ellman, J. A., 2002 6月 12, In: Journal of the American Chemical Society. 124, 23, p. 6518-6519 2 p.

  研究成果: Article › 査読

  • Amino alcohols 100%
  • Amino Alcohols 91%
  • Imines 74%
  • Aldehydes 72%
  • Imine 45%
  129 被引用数 (Scopus)

• Asymmetric α-alkylation of N′-tert-butanesulfinyl amidines. Application to the total synthesis of (6 R,7 S)-7-amino-7,8-dihydro-α- bisabolene

  Kochi, T. & Ellman, J. A., 2004 12月 8, In: Journal of the American Chemical Society. 126, 48, p. 15652-15653 2 p.

  研究成果: Article › 査読
  99 被引用数 (Scopus)

• Carbon–Carbon Bond Formation via Catalytically Generated Aminocarbene Complexes: Rhodium-Catalyzed Hydroaminative Cyclization of Enynes with Secondary Amines

  Takano, S., Shiomi, R., Morimoto, Y., Kochi, T. & Kakiuchi, F., 2020 7月 13, In: Angewandte Chemie - International Edition. 59, 29, p. 11754-11757 4 p.

  研究成果: Article › 査読

  • Cyclization 100%
  • Rhodium 88%
  • Enyne 72%
  • Amines 67%
  • Secondary Amine 56%
  4 被引用数 (Scopus)

• Catalytic, Directed C-C Bond Functionalization of Styrenes

  Onodera, S., Togashi, R., Ishikawa, S., Kochi, T. & Kakiuchi, F., 2020 4月 22, In: Journal of the American Chemical Society. 142, 16, p. 7345-7349 5 p.

  研究成果: Article › 査読

  • Styrenes 100%
  • Alkenes 70%
  • Styrene 50%
  • Carbon 44%
  • Rhodium 39%
  12 被引用数 (Scopus)

• Catalytic electrochemical C-H iodination and one-pot arylation by ON/OFF switching of electric current

  Aiso, H., Kochi, T., Mutsutani, H., Tanabe, T., Nishiyama, S. & Kakiuchi, F., 2012 9月 7, In: Journal of Organic Chemistry. 77, 17, p. 7718-7724 7 p.

  研究成果: Article › 査読

  • Current 100%
  • Arylation 84%
  • Palladium 59%
  • Aryl Group 44%
  • Catalyst 32%
  89 被引用数 (Scopus)

• Catalytic Formation of α-Aryl Ketones by C-H Functionalization with Cyclic Alkenyl Carbonates and One-Pot Synthesis of Isocoumarins

  Hara, Y., Onodera, S., Kochi, T. & Kakiuchi, F., 2015 10月 2, In: Organic Letters. 17, 19, p. 4850-4853 4 p.

  研究成果: Article › 査読

  • Isocoumarins 100%
  • Rhodium 93%
  • Cyclization 79%
  • Carbonates 75%
  • Aromatic Amide 74%
  47 被引用数 (Scopus)

• Catalytic Reactions of Terminal Alkynes Using Rhodium(I) Complexes Bearing 8-Quinolinolate Ligands

  Kakiuchi, F., Takano, S. & Kochi, T., 2018 7月 6, In: ACS Catalysis. 8, 7, p. 6127-6137 11 p.

  研究成果: Article › 査読

  • Rhodium 100%
  • Cycloaddition 87%
  • Ligands 86%
  • Transition metals 63%
  • Alkyne 56%
  13 被引用数 (Scopus)

• Chain Walking as a Strategy for Carbon-Carbon Bond Formation at Unreactive Sites in Organic Synthesis: Catalytic Cycloisomerization of Various 1,n-Dienes

  Hamasaki, T., Aoyama, Y., Kawasaki, J., Kakiuchi, F. & Kochi, T., 2015 12月 30, In: Journal of the American Chemical Society. 137, 51, p. 16163-16171 9 p.

  研究成果: Article › 査読

  • Synthetic Chemistry Techniques 100%
  • Cycloisomerization 77%
  • Carbon 59%
  • Olefins 57%
  • Alkenes 56%
  64 被引用数 (Scopus)

• Chain-walking cycloisomerization of 1,n-dienes catalyzed by pyridine-oxazoline palladium catalysts and its application to asymmetric synthesis

  Hamasaki, T., Kakiuchi, F. & Kochi, T., 2016, In: Chemistry Letters. 45, 3, p. 297-299 3 p.

  研究成果: Article › 査読

  • Cycloisomerization 100%
  • Palladium 58%
  • Cyclopentane 46%
  • Ligand 33%
  • Catalyst 32%
  12 被引用数 (Scopus)

• Chain-walking strategy for organic synthesis: Catalytic cycloisomerization of 1,n-dienes

  Kochi, T., Hamasaki, T., Aoyama, Y., Kawasaki, J. & Kakiuchi, F., 2012 10月 10, In: Journal of the American Chemical Society. 134, 40, p. 16544-16547 4 p.

  研究成果: Article › 査読

  • Synthetic Chemistry Techniques 100%
  • Cycloisomerization 77%
  • Carbon 59%
  • Walking 52%
  • bicyclo(4.3.0)nonane 49%
  102 被引用数 (Scopus)

• Chelation- assisted catalytic C- C, C- Si, and C- halogen bond formation by substitution via the cleavage of C(sp²)- H and C(sp³)- H bonds

  Kakiuchi, F. & Kochi, T., 2015, In: Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry. 73, 11, p. 1099-1110 12 p.

  研究成果: Article › 査読

  • Arylation 100%
  • Halogen 81%
  • Cleavage 63%
  • Carbamoyl 59%
  • Acyl Chloride 58%
  5 被引用数 (Scopus)

• Chelation-Assisted Regioselective Catalytic Functionalization of C-H, C-O, C-N and C-F Bonds

  Kakiuchi, F., Kochi, T. & Murai, S., 2014 10月 22, In: Synlett. 25, 17, p. 2390-2414 25 p., st-2014-a0613-a.

  研究成果: Article › 査読

  • Cleavage 100%
  • Anthracenes 81%
  • Pentacenes 49%
  • Arene 46%
  • Olefinic Compound 44%
  79 被引用数 (Scopus)

• Cleavage of C-N bonds in aniline derivatives on a ruthenium center and its relevance to catalytic C-C bond formation

  Koreeda, T., Kochi, T. & Kakiuchi, F., 2009 6月 3, In: Journal of the American Chemical Society. 131, 21, p. 7238-7239 2 p.

  研究成果: Article › 査読

  • Ruthenium 100%
  • Aniline 98%
  • aniline 91%
  • Derivatives 51%
  • Cleavage 43%
  100 被引用数 (Scopus)

• Control of product selectivity by a styrene additive in ruthenium-catalyzed C-H arylation

  Hiroshima, S., Matsumura, D., Kochi, T. & Kakiuchi, F., 2010 11月 19, In: Organic Letters. 12, 22, p. 5318-5321 4 p.

  研究成果: Article › 査読

  • Ruthenium 100%
  • Styrene 88%
  • ruthenium 77%
  • styrenes 71%
  • Arylation 68%
  34 被引用数 (Scopus)

• Convenient synthesis of Dibenzo[a, h]anthracenes and picenes via C-H arylation of acetophenones with arenediboronates

  Kitazawa, K., Kochi, T., Nitani, M., Ie, Y., Aso, Y. & Kakiuchi, F., 2011, In: Chemistry Letters. 40, 3, p. 300-302 3 p.

  研究成果: Article › 査読

  • Cycloaromatization 100%
  • Anthracenes 88%
  • Acetophenones 81%
  • Aromatic Ketone 78%
  • Ethynyl 75%
  35 被引用数 (Scopus)

• Convenient synthesis of Tetra- And hexaarylanthracenes by means of RuH2(CO)(PPh3)3-Catalyzed C-H Arylation of Anthraquinone with Arylboronates

  Kitazawa, K., Kochi, T., Sato, M. & Kakiuchi, F., 2009 5月 7, In: Organic Letters. 11, 9, p. 1951-1954 4 p.

  研究成果: Article › 査読

  • anthraquinones 100%
  • Anthraquinones 92%
  • Anthraquinone 71%
  • Arylation 71%
  • Carbon Monoxide 66%
  53 被引用数 (Scopus)

• Copper-Catalyzed Electrochemical Chlorination of 1,3-Dicarbonyl Compounds Using Hydrochloric Acid

  Tsuchida, K., Kochi, T. & Kakiuchi, F., 2013 11月, In: Asian Journal of Organic Chemistry. 2, 11, p. 935-937 3 p.

  研究成果: Article › 査読
  20 被引用数 (Scopus)

• Deuterium-Labeling Studies on the C-H/Olefin Coupling of Aromatic Ketones Catalyzed by Fe(PMe ₃) ₄

  Kimura, N., Katta, S., Kitazawa, Y., Kochi, T. & Kakiuchi, F., 2021 9月 16, In: Synthesis (Germany). 53, 18, p. 3383-3389 7 p.

  研究成果: Article › 査読

  • Deuterium 100%
  • Ketones 99%
  • Aromatic Ketone 86%
  • Olefins 83%
  • Labeling 67%

• Development and application of a new general method for the asymmetric synthesis of syn- and anti-1,3-amino alcohols

  Kochi, T., Tang, T. P. & Ellman, J. A., 2003 9月 17, In: Journal of the American Chemical Society. 125, 37, p. 11276-11282 7 p.

  研究成果: Article › 査読

  • Amino alcohols 100%
  • Amino Alcohols 91%
  • Imines 74%
  • Imine 45%
  • Aldehydes 36%
  160 被引用数 (Scopus)

• Development and application of efficient methods for extension of π-conjugated systems by catalytic substitution reactions via chelation-assisted cleavage of unreactive aromatic carbon bonds

  Kochi, T. & Kakiuchi, F., 2013 9月 24, In: Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry. 71, 6, p. 588-600 13 p.

  研究成果: Article › 査読

  • Anthracenes 100%
  • Pentacenes 60%
  • Aromatic Bond 59%
  • Alkenyl Group 52%
  • Cleavage 48%
  3 被引用数 (Scopus)

• Direct Alkenylation of Allylbenzenes via Chelation-Assisted C-C Bond Cleavage

  Onodera, S., Ishikawa, S., Kochi, T. & Kakiuchi, F., 2018 8月 8, In: Journal of the American Chemical Society. 140, 31, p. 9788-9792 5 p.

  研究成果: Article › 査読

  • Alkenylation 100%
  • Allylbenzene Derivatives 89%
  • Chelation 61%
  • Styrenes 44%
  • Rhodium 35%
  53 被引用数 (Scopus)

• Efficient synthesis of 3,6,13,16-tetrasubstituted-tetrabenzo[a,d,j,m]coronenes by selective C–H/C–O arylations of anthraquinone derivatives

  Terai, S., Sato, Y., Kochi, T. & Kakiuchi, F., 2020 3月 31, In: Beilstein Journal of Organic Chemistry. 16, p. 544-550 7 p.

  研究成果: Article › 査読

  Open Access

  • Coronene 100%
  • Anthraquinone 80%
  • Arylation 79%
  • Methylenation 27%
  • Oxidative Cyclization 22%

• Formation of linear copolymers of ethylene and acrylonitrile catalyzed by phosphine sulfonate palladium complexes

  Kochi, T., Noda, S., Yoshimura, K. & Nozaki, K., 2007 7月 25, In: Journal of the American Chemical Society. 129, 29, p. 8948-8949 2 p.

  研究成果: Article › 査読

  • phosphine 100%
  • Acrylonitrile 92%
  • Palladium 89%
  • ethylene 80%
  • Copolymers 69%
  229 被引用数 (Scopus)

• In Situ Generation of Ruthenium Carbonyl Phosphine Complexes as a Versatile Method for the Development of Enantioselective C−O Bond Arylation

  Kondo, H., Kochi, T. & Kakiuchi, F., 2020 2月 6, In: Chemistry - A European Journal. 26, 8, p. 1737-1741 5 p.

  研究成果: Article › 査読

  • Ruthenium 100%
  • Ligands 88%
  • Arylation 72%
  • Phosphine 59%
  • Catalysts 56%
  1 被引用数 (Scopus)

• Iron-Catalyzed Ortho C-H Homoallylation of Aromatic Ketones with Methylenecyclopropanes

  Kimura, N., Katta, S., Kitazawa, Y., Kochi, T. & Kakiuchi, F., 2021 3月 31, In: Journal of the American Chemical Society. 143, 12, p. 4543-4549 7 p.

  研究成果: Article › 査読

  • methylenecyclopropane 100%
  • Ketones 65%
  • Aromatic Ketone 57%
  • Iron 41%
  • 1,2-dihydronaphthalene 34%
  7 被引用数 (Scopus)

• Iron-Catalyzed Ortho-Selective C−H Alkylation of Aromatic Ketones with N-Alkenylindoles and Partial Indolylation via 1,4-Iron Migration

  Kimura, N., Kochi, T. & Kakiuchi, F., 2019 7月, In: Asian Journal of Organic Chemistry. 8, 7, p. 1115-1117 3 p.

  研究成果: Article › 査読

  • Aromatic Ketone 100%
  • Catalyst 33%
  10 被引用数 (Scopus)

• Iron-Catalyzed Regioselective Anti-Markovnikov Addition of C-H Bonds in Aromatic Ketones to Alkenes

  Kimura, N., Kochi, T. & Kakiuchi, F., 2017 10月 25, In: Journal of the American Chemical Society. 139, 42, p. 14849-14852 4 p.

  研究成果: Article › 査読

  • Alkenes 100%
  • Ketones 91%
  • Aromatic Ketone 79%
  • Olefins 76%
  • Regioselectivity 66%
  47 被引用数 (Scopus)

• Mechanistic studies on the formation of linear polyethylene chain catalyzed by palladium phosphine-sulfonate complexes: Experiment and theoretical studies

  Noda, S., Nakamura, A., Kochi, T., Lung, W. C., Morokuma, K. & Nozaki, K., 2009 10月 7, In: Journal of the American Chemical Society. 131, 39, p. 14088-14100 13 p.

  研究成果: Article › 査読

  • phosphine 100%
  • Palladium 89%
  • ethylene 80%
  • Polyethylene 67%
  • Polyethylenes 62%
  119 被引用数 (Scopus)

• Metal-Catalyzed Sequential Formation of Distant Bonds in Organic Molecules: Palladium-Catalyzed Hydrosilylation/Cyclization of 1,n-Dienes by Chain Walking

  Kochi, T., Ichinose, K., Shigekane, M., Hamasaki, T. & Kakiuchi, F., 2019 4月 8, In: Angewandte Chemie - International Edition. 58, 16, p. 5261-5265 5 p.

  研究成果: Article › 査読

  • Hydrosilylation 100%
  • Cyclization 87%
  • Palladium 65%
  • Molecules 48%
  • Organic Molecule 46%
  19 被引用数 (Scopus)

• New strategy for catalytic oxidative CH functionalization: Efficient combination of transition-metal catalyst and electrochemical oxidation

  Kakiuchi, F. & Kochi, T., 2020 10月, In: Chemistry Letters. 49, 10, p. 1256-1269 14 p.

  研究成果: Article › 査読

  Open Access

  • Electrochemical Oxidation 100%
  11 被引用数 (Scopus)

• Palladium-catalyzed aromatic C-H halogenation with hydrogen halides by means of electrochemical oxidation

  Kakiuchi, F., Kochi, T., Mutsutani, H., Kobayashi, N., Urano, S., Sato, M., Nishiyama, S. & Tanabe, T., 2009 8月 19, In: Journal of the American Chemical Society. 131, 32, p. 11310-11311 2 p.

  研究成果: Article › 査読

  • Halogenation 100%
  • Electrochemical oxidation 82%
  • Palladium 76%
  • Hydrogen Halide 68%
  • Hydrogen 58%
  243 被引用数 (Scopus)

• Palladium-Catalyzed C−H Iodination of N-(8-Quinolinyl)benzamide Derivatives Under Electrochemical and Non-Electrochemical Conditions

  Sano, K., Kimura, N., Kochi, T. & Kakiuchi, F., 2018 7月, In: Asian Journal of Organic Chemistry. 7, 7, p. 1311-1314 4 p.

  研究成果: Article › 査読

  • Benzamides 100%
  • Benzamide 90%
  • Anodizing 73%
  • Reaction Yield 30%
  9 被引用数 (Scopus)

• Palladium-Catalyzed ortho-Selective C-H Chlorination of Benzamide Derivatives under Anodic Oxidation Conditions

  Konishi, M., Tsuchida, K., Sano, K., Kochi, T. & Kakiuchi, F., 2017 8月 18, In: Journal of Organic Chemistry. 82, 16, p. 8716-8724 9 p.

  研究成果: Article › 査読

  • Vismodegib 100%
  • Benzamide 60%
  • Anodizing 49%
  • Acid 17%
  58 被引用数 (Scopus)

• Palladium-catalyzed regioselective homocoupling of arenes using anodic oxidation: Formal electrolysis of aromatic carbon-hydrogen bonds

  Saito, F., Aiso, H., Kochi, T. & Kakiuchi, F., 2014 11月 24, In: Organometallics. 33, 22, p. 6704-6707 4 p.

  研究成果: Article › 査読

  • dimerization 100%
  • electrolysis 92%
  • palladium 85%
  • hydrogen bonds 83%
  • Anodizing 77%
  72 被引用数 (Scopus)

• Palladium-Catalyzed Remote Diborylative Cyclization of Dienes with Diborons via Chain Walking

  Kanno, S., Kakiuchi, F. & Kochi, T., 2021 11月 24, In: Journal of the American Chemical Society. 143, 46, p. 19275-19281 7 p.

  研究成果: Article › 査読

  • Cyclization 100%
  • Boryl Group 94%
  • Palladium 87%
  • Cyclopentane 69%
  • Reagents 68%
  3 被引用数 (Scopus)

• Pd-catalyzed copolymerization of methyl acrylate with carbon monoxide: Structures, properties and mechanistic aspects toward ligand design

  Nakamura, A., Munakata, K., Ito, S., Kochi, T., Chung, L. W., Morokuma, K. & Nozaki, K., 2011 5月 4, In: Journal of the American Chemical Society. 133, 17, p. 6761-6779 19 p.

  研究成果: Article › 査読

  • methyl acrylate 100%
  • Copolymerization 77%
  • Ligands 71%
  • Palladium 65%
  • Methyl Acrylate 60%
  51 被引用数 (Scopus)

• Regiocontrolled copolymerization of methyl acrylate with carbon monoxide

  Nakamura, A., Munakata, K., Kochi, T. & Nozaki, K., 2008 7月 2, In: Journal of the American Chemical Society. 130, 26, p. 8128-8129 2 p.

  研究成果: Article › 査読

  • methyl acrylate 100%
  • Copolymerization 77%
  • Copolymers 63%
  • Methyl Acrylate 60%
  • Carbon monoxide 58%
  37 被引用数 (Scopus)

• Remote Arylative Substitution of Alkenes Possessing an Acetoxy Group via β-Acetoxy Elimination

  Muto, K., Kumagai, T., Kakiuchi, F. & Kochi, T., 2021 11月 8, In: Angewandte Chemie - International Edition. 60, 46, p. 24500-24504 5 p.

  研究成果: Article › 査読

  • Olefins 100%
  • Substitution reactions 82%
  • Alkene 59%
  • Substitution Reaction 52%
  • Acids 38%
  1 被引用数 (Scopus)

• Rh₄S₇ and Ir₃CuS₆ clusters with Di- and trisulfido ligands derived from dinuclear hydrogensulfido complexes

  Kochi, T., Tanabe, Y., Tang, Z., Ishii, Y. & Hidai, M., 1999, In: Chemistry Letters. 12, p. 1279-1280 2 p.

  研究成果: Article › 査読

  • Molecular Cluster 100%
  • Ligand 67%
  8 被引用数 (Scopus)

• Rhodium-catalyzed anti-markovnikov addition of secondary amines to arylacetylenes at room temperature

  Sakai, K., Kochi, T. & Kakiuchi, F., 2011 8月 5, In: Organic Letters. 13, 15, p. 3928-3931 4 p.

  研究成果: Article › 査読

  • Rhodium 100%
  • Alkynes 91%
  • Arylacetylene 84%
  • bulbs 74%
  • rhodium 73%
  36 被引用数 (Scopus)

• Rhodium-Catalyzed Anti-Markovnikov Hydroamination of Aliphatic and Aromatic Terminal Alkynes with Aliphatic Primary Amines

  Morimoto, Y., Kochi, T. & Kakiuchi, F., 2021 9月 17, In: Journal of Organic Chemistry. 86, 18, p. 13143-13152 10 p.

  研究成果: Article › 査読

  • Bromo Group 100%
  • Primary Aliphatic Amine 90%
  • Hydroamination 83%
  • Aldimine 81%
  • Thioester 76%
  1 被引用数 (Scopus)

• Rhodium-catalyzed anti-Markovnikov intermolecular hydroalkoxylation of terminal acetylenes

  Kondo, M., Kochi, T. & Kakiuchi, F., 2011 1月 12, In: Journal of the American Chemical Society. 133, 1, p. 32-34 3 p.

  研究成果: Article › 査読

  • Rhodium 100%
  • Alkynes 91%
  • Ethers 88%
  • Acetylene 75%
  • Metals 48%
  72 被引用数 (Scopus)

• Rhodium-catalyzed dimerization of arylacetylenes and addition of malonates to 1,3-enynes

  Mochizuki, K., Sakai, K., Kochi, T. & Kakiuchi, F., 2013, In: Synthesis (Germany). 45, 15, p. 2088-2092 5 p., SS-2013-C0135-ST.

  研究成果: Article › 査読

  • Dimerization 100%
  • Rhodium 91%
  • Arylacetylene 88%
  • Alkyne 34%
  • Catalysts 33%
  16 被引用数 (Scopus)

• Rhodium-catalyzed intermolecular [2 + 2] cycloaddition of terminal alkynes with electron-deficient alkenes

  Sakai, K., Kochi, T. & Kakiuchi, F., 2013 3月, In: Organic Letters. 15, 5, p. 1024-1027 4 p.

  研究成果: Article › 査読

  • Rhodium 100%
  • phosphine 95%
  • Cycloaddition Reaction 93%
  • alkynes 93%
  • Alkynes 91%
  52 被引用数 (Scopus)

• Room-temperature regioselective c-H/olefin coupling of aromatic ketones using an activated ruthenium catalyst with a carbonyl ligand and structural elucidation of key intermediates

  Kakiuchi, F., Kochi, T., Mizushima, E. & Murai, S., 2010 12月 22, In: Journal of the American Chemical Society. 132, 50, p. 17741-17750 10 p.

  研究成果: Article › 査読

  • Ruthenium 100%
  • Alkenes 98%
  • Ketones 89%
  • Ligands 83%
  • Aromatic Ketone 78%
  92 被引用数 (Scopus)

• RuH₂(CO)(PPh₃)₃-catalyzed arylation of aromatic esters using arylboronates via C-H bond cleavages

  Kitazawa, K., Kotani, M., Kochi, T., Langeloth, M. & Kakiuchi, F., 2010 4月 15, In: Journal of Organometallic Chemistry. 695, 8, p. 1163-1167 5 p.

  研究成果: Article › 査読

  • pinacolone 100%
  • Aromatic Ester 58%
  • esters 47%
  • Esters 45%
  • Arylation 45%
  20 被引用数 (Scopus)