(12,17-diethoxycarbonyl-11,18-dimethyl-2,3:6,7-dibutanocorrphycenato) copper(II)-12,17-diethoxycarbonyl-11,18-dimethyl-2:3,6:7-dibutanocorrphycene(3/ 97)

Yoshiki Ohgo, Yuki Yokoyama, Daisuke Hashizume, Saburo Neya, Mikio Nakamura

研究成果: Article査読

2 被引用数 (Scopus)


The corrphycene molecule of the title compound, [Cu(C 36H 36- N 4O 4)] 36H 38N 4O 4, has an essentially planar macrocyclic framwork with a slightly distorted trapezoidal N 4 core; the r.m.s. deviation of the peripheral 20 C atoms and four N atoms is 0.054(3) Å. The surface area within the N 4 - coordinating core (8.358 Å 2) is significantly smaller than that (8.503 Å 2) of the corresponding free-base porphyrin. Two intramolecular N-H··· N hydrogen bonds are observed. Detailed structure analysis clarified that the co-crystallization of the free-base corrphycene together with a quite minor component (ca 3%) of corrphycenato-Cu II occurred in the recrystallization process.

ジャーナルActa Crystallographica Section E: Structure Reports Online
出版ステータスPublished - 2012 1

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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