1,4-Asymmetric induction using a cobalt alkyne complex

Yujiro Hayashi; Hirofumi Yamaguchi; Maya Toyoshima; Satoshi Nasu; Koji Ochiai; Mitsuru Shoji

doi:10.1021/om700961e

1,4-Asymmetric induction using a cobalt alkyne complex

Yujiro Hayashi, Hirofumi Yamaguchi, Maya Toyoshima, Satoshi Nasu, Koji Ochiai, Mitsuru Shoji

薬科学科

研究成果: Article › 査読

13 被引用数 (Scopus)

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Remote stereocontrol is a difficult topic in current organic synthesis. We have developed a highly diastereoselective 1,4-asymmetric induction using a cobalt alkyne complex. This is the first example of using a cobalt alkyne complex for a stereoselective reaction via 1,4-chelation. Both anti and syn isomers were stereoselectively synthesized using two different methods.

本文言語	English
ページ（範囲）	163-165
ページ数	3
ジャーナル	Organometallics
巻	27
号	2
DOI	https://doi.org/10.1021/om700961e
出版ステータス	Published - 2008 1月 28

ASJC Scopus subject areas

物理化学および理論化学
有機化学
無機化学

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AU - Shoji, Mitsuru

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1,4-Asymmetric induction using a cobalt alkyne complex

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