(+)-(1S,2S,4S,4aR,5R,6S,9S,10S)-4-Benzyloxy-9,10-(carbonyldioxy) -1-methoxymethoxy-4a,6,-8,8-tetramethyl-7-methylenedodecahydro-6, 9-ethanobenzocyclooctene-5-ol

Shigeru Ohba, Ayako Chinen, Yuki Matsumoto, Noritaka Chida

研究成果: Article

3 引用 (Scopus)

抄録

The title tetracyclic compound, C29H40O7, has been obtained unexpectedly in a synthetic study of the natural diterpenoid, paclitaxel. There is an intramolecular O-H⋯O hydrogen bond between the hydroxy and benzyloxy groups.

元の言語English
ジャーナルActa Crystallographica Section E: Structure Reports Online
59
発行部数10
DOI
出版物ステータスPublished - 2003 10

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Diterpenes
Paclitaxel
Hydrogen
Hydrogen bonds
hydrogen bonds

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Structural Biology

これを引用

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title = "(+)-(1S,2S,4S,4aR,5R,6S,9S,10S)-4-Benzyloxy-9,10-(carbonyldioxy) -1-methoxymethoxy-4a,6,-8,8-tetramethyl-7-methylenedodecahydro-6, 9-ethanobenzocyclooctene-5-ol",
abstract = "The title tetracyclic compound, C29H40O7, has been obtained unexpectedly in a synthetic study of the natural diterpenoid, paclitaxel. There is an intramolecular O-H⋯O hydrogen bond between the hydroxy and benzyloxy groups.",
author = "Shigeru Ohba and Ayako Chinen and Yuki Matsumoto and Noritaka Chida",
year = "2003",
month = "10",
doi = "10.1107/S1600536803019871",
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journal = "Acta Crystallographica Section E: Structure Reports Online",
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publisher = "International Union of Crystallography",
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TY - JOUR

T1 - (+)-(1S,2S,4S,4aR,5R,6S,9S,10S)-4-Benzyloxy-9,10-(carbonyldioxy) -1-methoxymethoxy-4a,6,-8,8-tetramethyl-7-methylenedodecahydro-6, 9-ethanobenzocyclooctene-5-ol

AU - Ohba, Shigeru

AU - Chinen, Ayako

AU - Matsumoto, Yuki

AU - Chida, Noritaka

PY - 2003/10

Y1 - 2003/10

N2 - The title tetracyclic compound, C29H40O7, has been obtained unexpectedly in a synthetic study of the natural diterpenoid, paclitaxel. There is an intramolecular O-H⋯O hydrogen bond between the hydroxy and benzyloxy groups.

AB - The title tetracyclic compound, C29H40O7, has been obtained unexpectedly in a synthetic study of the natural diterpenoid, paclitaxel. There is an intramolecular O-H⋯O hydrogen bond between the hydroxy and benzyloxy groups.

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DO - 10.1107/S1600536803019871

M3 - Article

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JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

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