抄録
4-O-Benzyl-23-O-isopropylidene-L-threose readily available from L-tartaric acid is a quite useful four-carbon building block for monosaccharide synthesis. The versatility can be reinforced by the coupled use of stereoselective addition reactions where the suitable choice of organometallics leads to highly anti-selective additions. The building block is particularly useful in the synthesis of rare sugars the versatility of which is demonstrated by the synthesis of some L-sugars as well as the formal total synthesis of polyoxin J in convergent manner.
本文言語 | English |
---|---|
ページ(範囲) | 265-276 |
ページ数 | 12 |
ジャーナル | Tetrahedron |
巻 | 46 |
号 | 1 |
DOI | |
出版ステータス | Published - 1990 |
外部発表 | はい |
ASJC Scopus subject areas
- 生化学
- 創薬
- 有機化学