A convergent total synthesis of epolactaene: An application of the bridgehead oxiranyl anion strategy

Kouji Kuramochi, Seigo Nagata, Hideyoshi Itaya, Yasuaki Matsubara, Takashi Sunoki, Hiromi Uchiro, Ken Ichi Takao, Susumu Kobayashi

研究成果: Article査読

40 被引用数 (Scopus)

抄録

The generation and reaction of a lactone-derived oxiranyl anion is described. The aldol-type reaction of the epoxylactone and aldehydes was accomplished by a two-step procedure via the trimethylsilyl epoxylactone. The application of this methodology to the total synthesis of (+)-epolactaene and its analogs is described.

本文言語English
ページ(範囲)9743-9758
ページ数16
ジャーナルTetrahedron
59
49
DOI
出版ステータスPublished - 2003 12 1

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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