A designer ligand field for blue-green luminescence of organoeuropium(II) sandwich complexes with cyclononatetraenyl ligands

Kenshiro Kawasaki; Rion Sugiyama; Takashi Tsuji; Takeshi Iwasa; Hironori Tsunoyama; Yoshiyuki Mizuhata; Norihiro Tokitoh; Atsushi Nakajima

doi:10.1039/c7cc03045b

A designer ligand field for blue-green luminescence of organoeuropium(II) sandwich complexes with cyclononatetraenyl ligands

Kenshiro Kawasaki, Rion Sugiyama, Takashi Tsuji, Takeshi Iwasa, Hironori Tsunoyama, Yoshiyuki Mizuhata, Norihiro Tokitoh, Atsushi Nakajima

化学科

研究成果: Article

10 引用（Scopus）

抜粋

A novel η⁹-coordinated double-decker sandwich complex of divalent europium is synthesized. The complex exhibits blue-green photoluminescence at 516 nm, which is significantly blue-shifted from those of other organoeuropium(II) sandwich complexes (∼630 nm). The blue-shift was quantitatively explained by the weakened electrostatic field of the expanded 10-π ring.

元の言語	English
ページ（範囲）	6557-6560
ページ数	4
ジャーナル	Chemical Communications
巻	53
発行部数	49
DOI	https://doi.org/10.1039/c7cc03045b
出版物ステータス	Published - 2017 1 1

フィンガープリント

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

これを引用

Kawasaki, K., Sugiyama, R., Tsuji, T., Iwasa, T., Tsunoyama, H., Mizuhata, Y., Tokitoh, N., & Nakajima, A. (2017). A designer ligand field for blue-green luminescence of organoeuropium(II) sandwich complexes with cyclononatetraenyl ligands. Chemical Communications, 53(49), 6557-6560. https://doi.org/10.1039/c7cc03045b

A designer ligand field for blue-green luminescence of organoeuropium(II) sandwich complexes with cyclononatetraenyl ligands. / Kawasaki, Kenshiro; Sugiyama, Rion; Tsuji, Takashi; Iwasa, Takeshi; Tsunoyama, Hironori; Mizuhata, Yoshiyuki; Tokitoh, Norihiro; Nakajima, Atsushi.

：: Chemical Communications, 巻 53, 番号 49, 01.01.2017, p. 6557-6560.

研究成果: Article

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AU - Iwasa, Takeshi

AU - Tsunoyama, Hironori

AU - Mizuhata, Yoshiyuki

AU - Tokitoh, Norihiro

AU - Nakajima, Atsushi

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AB - A novel η9-coordinated double-decker sandwich complex of divalent europium is synthesized. The complex exhibits blue-green photoluminescence at 516 nm, which is significantly blue-shifted from those of other organoeuropium(II) sandwich complexes (∼630 nm). The blue-shift was quantitatively explained by the weakened electrostatic field of the expanded 10-π ring.

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文献にアクセス

10.1039/c7cc03045b