A neutral Fe(iii) compound exhibiting a two-step spin transition and dielectric anomalies

Zhao Yang Li, Jing Wei Dai, Kevin J. Gagnon, Hong Ling Cai, Takashi Yamamoto, Yasuaki Einaga, Han Hua Zhao, Shinji Kanegawa, Osamu Sato, Kim R. Dunbar, Ren Gen Xiong

研究成果: Article査読

26 被引用数 (Scopus)

抄録

The mononuclear ferric compound Fe(H-5-Cl-thsa-Me)(5-Cl-thsa-Me) ·H2O (1) was synthesized and characterized using powder/single-crystal X-ray diffraction, Mössbauer spectroscopy, differential scanning calorimetry (DSC), and magnetic susceptibility measurements. This photo-responsive compound shows reversible, two-step spin-crossover behaviour. Moreover, dielectric anomalies were observed during the spin transitions, demonstrating the multifunctional properties of compound 1.

本文言語English
ページ(範囲)14685-14688
ページ数4
ジャーナルDalton Transactions
42
41
DOI
出版ステータスPublished - 2013 11月 7

ASJC Scopus subject areas

  • 無機化学

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