A new synthetic route to heteroarylsilanes via ruthenium-catalyzed C-H/SiR3 coupling

Fumitoshi Kakiuchi, Mitsutaka Matsumoto, Motohiro Sonoda, Takahide Fukuyama, Naoto Chatani, Shinji Murai, Naoyuki Furukawa, Yoshio Seki

研究成果: Article

62 引用 (Scopus)

抜粋

Heteroarylsilanes can be synthesized by the reaction of heteroaromatic compounds with triorganovinylsilanes with the aid of a Ru3(CO)12-catalyst. A variety of heteroaromatic compounds can be used in this C-H/SiR3 coupling. The coupling reaction was observed to take place at a position β to the directing carbonyl group, e.g., ketone, ester, and amide, in the case of heteroaromatic compounds.

元の言語English
ページ(範囲)750-751
ページ数2
ジャーナルChemistry Letters
発行部数7
DOI
出版物ステータスPublished - 2000 1 1

    フィンガープリント

ASJC Scopus subject areas

  • Chemistry(all)

これを引用

Kakiuchi, F., Matsumoto, M., Sonoda, M., Fukuyama, T., Chatani, N., Murai, S., Furukawa, N., & Seki, Y. (2000). A new synthetic route to heteroarylsilanes via ruthenium-catalyzed C-H/SiR3 coupling. Chemistry Letters, (7), 750-751. https://doi.org/10.1246/cl.2000.750