A new synthetic route to heteroarylsilanes via ruthenium-catalyzed C-H/SiR3 coupling

Fumitoshi Kakiuchi; Mitsutaka Matsumoto; Motohiro Sonoda; Takahide Fukuyama; Naoto Chatani; Shinji Murai; Naoyuki Furukawa; Yoshio Seki

doi:10.1246/cl.2000.750

A new synthetic route to heteroarylsilanes via ruthenium-catalyzed C-H/SiR₃ coupling

Fumitoshi Kakiuchi, Mitsutaka Matsumoto, Motohiro Sonoda, Takahide Fukuyama, Naoto Chatani, Shinji Murai, Naoyuki Furukawa, Yoshio Seki

研究成果: Article › 査読

67 被引用数 (Scopus)

抄録

Heteroarylsilanes can be synthesized by the reaction of heteroaromatic compounds with triorganovinylsilanes with the aid of a Ru₃(CO)₁₂-catalyst. A variety of heteroaromatic compounds can be used in this C-H/SiR₃ coupling. The coupling reaction was observed to take place at a position β to the directing carbonyl group, e.g., ketone, ester, and amide, in the case of heteroaromatic compounds.

本文言語	English
ページ（範囲）	750-751
ページ数	2
ジャーナル	Chemistry Letters
号	7
DOI	https://doi.org/10.1246/cl.2000.750
出版ステータス	Published - 2000
外部発表	はい

ASJC Scopus subject areas

化学 (全般)

文献へのアクセス

10.1246/cl.2000.750

他のファイルとリンク

引用スタイル

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AU - Kakiuchi, Fumitoshi

AU - Matsumoto, Mitsutaka

AU - Sonoda, Motohiro

AU - Fukuyama, Takahide

AU - Chatani, Naoto

AU - Murai, Shinji

AU - Furukawa, Naoyuki

AU - Seki, Yoshio

PY - 2000

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AB - Heteroarylsilanes can be synthesized by the reaction of heteroaromatic compounds with triorganovinylsilanes with the aid of a Ru3(CO)12-catalyst. A variety of heteroaromatic compounds can be used in this C-H/SiR3 coupling. The coupling reaction was observed to take place at a position β to the directing carbonyl group, e.g., ketone, ester, and amide, in the case of heteroaromatic compounds.

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