A novel greener glycosidation using an acid-ionic liquid containing a protic acid

Kaname Sasaki, Hideyuki Nagai, Shuichi Matsumura, Kazunobu Toshima

研究成果: Article査読

56 被引用数 (Scopus)

抄録

The glycosidations of glucopyranosyl diethyl phosphite and alcohols using an ionic liquid, 1-n-hexyl-3-methylimidazolium trifluoromethanesulfonimidide (C6mim[NTf2]) containing a protic acid, trifluoromethanesulfonimide (HNTf2), as a novel solvent-catalyst system, effectively proceeded under mild conditions to give the corresponding glycosides in good to high yields. Furthermore, this acid-ionic liquid combination could be reused many times for the glycosidations without any loss in efficiency.

本文言語English
ページ(範囲)5605-5608
ページ数4
ジャーナルTetrahedron Letters
44
30
DOI
出版ステータスPublished - 2003 7 21

ASJC Scopus subject areas

  • 生化学
  • 創薬
  • 有機化学

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