A novel LIESST iron(II) complex exhibiting a high relaxation temperature

S. Hayami, Z. Z. Gu, Y. Einaga, Y. Kobayasi, Y. Ishikawa, Y. Yamada, A. Fujishima, O. Sato

研究成果: Article査読

115 被引用数 (Scopus)

抄録

The spin-crossover iron(II) complex [Fe(L)(CN)2·H2O (1) has been investigated. Complex 1 has a pentagonal bipyramidal structure which is seven-coordinated, containing an N3O2 macrocycle and two CN- ligands. Water molecules bind the complex by means of hydrogen bonding. It was found that the complex 1 exhibited a light-induced excited spin state trapping (LIESST) effect. The relaxation temperature is above 130 K, which is the highest temperature for LIESST compounds reported so far.

本文言語English
ページ(範囲)3240-3242
ページ数3
ジャーナルInorganic Chemistry
40
13
DOI
出版ステータスPublished - 2001 6月 18
外部発表はい

ASJC Scopus subject areas

  • 物理化学および理論化学
  • 無機化学

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