A redetermination of bis(N-methylethyl-enediamine-κ2/N, N′)bis(perchlorato-κO)-copper(II)

Takashiro Akitsu, Yasuaki Einaga

研究成果: Article査読

6 被引用数 (Scopus)

抄録

In the title compound, [Cu(ClO4)2(C3H 10N2)2], the Cu atom is located at a center of symmetry. Despite asymmetric introduction of TV-methyl groups into the ethylenediamine moieties, a second-order Jahn-Teller effect produces a typical semi-coordination trans-[CuN4(O2)] environment with long axial Cu - O bonds of 2.569 (2) Å. The Cu - N bond distances are 2.004 (2) and 2.057 (2) Å.

本文言語English
ページ(範囲)m991-m993
ジャーナルActa Crystallographica Section E: Structure Reports Online
59
11
DOI
出版ステータスPublished - 2003 11 1

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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