A solvent-directed stereoselective and electrocatalytic synthesis of diisoeugenol

Takashi Yamamoto, Barbara Riehl, Keisuke Naba, Kenshin Nakahara, Anton Wiebe, Tsuyoshi Saitoh, Siegfried R. Waldvogel, Yasuaki Einaga

研究成果: Article査読

32 被引用数 (Scopus)

抄録

A stereoselective and electrocatalytic coupling reaction of isoeugenol has been reported for the first time in a 1,1,1,3,3,3-hexafluoro-2-propanol (HFIP)/boron-doped diamond (BDD) electrode system. This particular C-C bond formation and diastereoselectivity is driven by a solvate interaction between the radical species and another isoeugenol molecule. Due to an electrocatalytic cycle, only understoichiometric amounts of charge are necessary. Since electric current is directly employed as the oxidant, the reaction is metal and reagent-free. In addition, the electrolysis can be conducted in a very simple undivided beaker-type cell under constant current conditions. Therefore, the protocol is easy to use, suitable for scale-up, and inherently safe.

本文言語English
ページ(範囲)2771-2773
ページ数3
ジャーナルChemical Communications
54
22
DOI
出版ステータスPublished - 2018

ASJC Scopus subject areas

  • 触媒
  • 電子材料、光学材料、および磁性材料
  • セラミックおよび複合材料
  • 化学 (全般)
  • 表面、皮膜および薄膜
  • 金属および合金
  • 材料化学

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