A synthetic study of (-)-dihydroedulan II and related compounds

Takeshi Sugai, Tomoki Yokochi, Naoyuki Watanabe, Hiromichi Ohta

研究成果: Article査読

17 被引用数 (Scopus)

抄録

(-)-Dihydroedulan II and related compounds were synthesized from (2R,1′RS)-dihydro-α-ionol, which was prepared by lipase-catalyzed enantioselective transesterification of the corresponding diastereomeric mixture as the key-step. Fungal allylic oxidation of (-)-dihydroedulan II worked well to afford a corresponding alcohol as well as (+)-dihydroedulan-8-one.

本文言語English
ページ(範囲)7227-7236
ページ数10
ジャーナルTetrahedron
47
35
DOI
出版ステータスPublished - 1991 8月 26

ASJC Scopus subject areas

  • 生化学
  • 創薬
  • 有機化学

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