AgAsF6 as safe alternative to AgClO4 for generating cationic zirconocene species: Utilities in lewis acid-promoted selective CC bond forming reactions

Keisuke Suzuki, Takayuki Hasegawa, Takahiro Imai, Hideki Maeta, Shigeru Ohba

研究成果: Article査読

46 被引用数 (Scopus)

抄録

For generating cationic zirconocene species that are useful for organic synthesis, AgAsF6 proved to be an efficient catalyst that serves as a safe alternative to AgClO4. Scope and limitation is discussed on this new catalyst in the processes including (1) alkyl/alkenyl transfer reaction from organozirconocene chloride to aldehyde, (2) two- and four-carbon homologation of aldehyde, (3) dual synthetic methods of 1,3-dienes from aldehydes/ketones via 1,3-bimetallic species, and (4) three-component alkylative cycloaddition via o-quinodimethane species.

本文言語English
ページ(範囲)4483-4494
ページ数12
ジャーナルTetrahedron
51
15
DOI
出版ステータスPublished - 1995 4 10

ASJC Scopus subject areas

  • 生化学
  • 創薬
  • 有機化学

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「AgAsF<sub>6</sub> as safe alternative to AgClO<sub>4</sub> for generating cationic zirconocene species: Utilities in lewis acid-promoted selective CC bond forming reactions」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

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