Alternate stacking of transition metal ions and terephthalic acid molecules for the fabrication of self-assembled multilayers

H. Sugimura, H. Yonezawa, S. Asai, Q. W. Sun, T. Ichii, K. H. Lee, K. Murase, K. Noda, K. Matsushige

研究成果: Article

6 引用 (Scopus)

抜粋

Self-assembled multilayers consisting of transition metal ions and biscarboxyl acid molecules have been fabricated by a layer-by-layer chemisorption technique. As transition metal ion, zirconium (Zr(IV)) or titanium (Ti(IV)) was employed, while terephthalic acid (TPA) was used as biscarboxyl molecule. In the multilayers, two TPA monolayers were bridged by one monolayer of Zr(IV) or Ti(IV) most likely through coordination bonds between the metal ions and the carboxyl groups in the TPA molecules. Although the both transition metal ions were successfully applied to construct multilayers, the multilayer structure of the Ti-TPA system was more disordered than that of the Zr-TPA system as revealed by grazing incidence X-ray reflectivity.

元の言語English
ページ(範囲)249-253
ページ数5
ジャーナルColloids and Surfaces A: Physicochemical and Engineering Aspects
321
発行部数1-3
DOI
出版物ステータスPublished - 2008 5 15
外部発表Yes

ASJC Scopus subject areas

  • Surfaces and Interfaces
  • Physical and Theoretical Chemistry
  • Colloid and Surface Chemistry

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