Alternating copolymerization of vinyl acetate with carbon monoxide

Takuya Kochi, Akifumi Nakamura, Hirotsugu Ida, Kyoko Nozaki

研究成果: Article査読

65 被引用数 (Scopus)

抄録

We report the first example of alternating copolymerization of a polar vinyl monomer and carbon monoxide using vinyl acetate. Alternating copolymers with high molecular weights were prepared employing palladium catalysts with phosphine-sulfonate bidentate ligands. NMR and MALDI-TOF MS analyses revealed that the obtained materials were alternating copolymers of vinyl acetate and carbon monoxide. This is also the first nonradical pathway for polymer synthesis with vinyl acetate, one of the most inexpensive and readily available polar vinyl monomer, as a major component.

本文言語English
ページ(範囲)7770-7771
ページ数2
ジャーナルJournal of the American Chemical Society
129
25
DOI
出版ステータスPublished - 2007 6 27
外部発表はい

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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