An enantioselective total synthesis and stereochemical revision of (+)-citrinadin B

Ke Kong, John A. Enquist, Monica E. McCallum, Genessa M. Smith, Takanori Matsumaru, Elnaz Menhaji-Klotz, John L. Wood

研究成果: Article査読

53 被引用数 (Scopus)

抄録

This manuscript describes an enantioselective synthesis of the naturally occurring alkaloid citrinadin B. The synthetic effort revealed an anomaly in the original structural assignment that has led to the proposal of a stereochemical revision. This revision is consistent with the structures previously reported for a closely related family of alkaloids, PF1270A-C. The synthesis is convergent and employs a stereoselective intermolecular nitrone cyloaddition reaction as a key step.

本文言語English
ページ(範囲)10890-10893
ページ数4
ジャーナルJournal of the American Chemical Society
135
30
DOI
出版ステータスPublished - 2013 7 31

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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