An enantioselective total synthesis and stereochemical revision of (+)-citrinadin B

Ke Kong; John A. Enquist; Monica E. McCallum; Genessa M. Smith; Takanori Matsumaru; Elnaz Menhaji-Klotz; John L. Wood

doi:10.1021/ja405548b

An enantioselective total synthesis and stereochemical revision of (+)-citrinadin B

Ke Kong, John A. Enquist, Monica E. McCallum, Genessa M. Smith, Takanori Matsumaru, Elnaz Menhaji-Klotz, John L. Wood

研究成果: Article › 査読

66 被引用数 (Scopus)

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This manuscript describes an enantioselective synthesis of the naturally occurring alkaloid citrinadin B. The synthetic effort revealed an anomaly in the original structural assignment that has led to the proposal of a stereochemical revision. This revision is consistent with the structures previously reported for a closely related family of alkaloids, PF1270A-C. The synthesis is convergent and employs a stereoselective intermolecular nitrone cyloaddition reaction as a key step.

本文言語	English
ページ（範囲）	10890-10893
ページ数	4
ジャーナル	Journal of the American Chemical Society
巻	135
号	30
DOI	https://doi.org/10.1021/ja405548b
出版ステータス	Published - 2013 7月 31
外部発表	はい

ASJC Scopus subject areas

触媒
化学 (全般)
生化学
コロイド化学および表面化学

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10.1021/ja405548b

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An enantioselective total synthesis and stereochemical revision of (+)-citrinadin B

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