An isocyanide probe for heme electronic structure: Bis(tert- butylisocyanide) complex of diazaporphyrin showing a unique (d xy)2(dxz, dyz)3 ground state

Yoshiki Ohgo, Saburo Neya, Hidehiro Uekusa, Mikio Nakamura

研究成果: Article査読

23 被引用数 (Scopus)

抄録

Isocyanide-bound model hemes always adopt the (dxz, d yz)4(dxy)1 ground state, however, we have found that the replacement of porphyrin by diazaporphyrin leads to the formation of an unprecedented low-spin bis(tert-butylisocyanide) complex with the (dxy)2(dxz, dyz)3 ground state.

本文言語English
ページ(範囲)4590-4592
ページ数3
ジャーナルChemical Communications
44
DOI
出版ステータスPublished - 2006

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

フィンガープリント 「An isocyanide probe for heme electronic structure: Bis(tert- butylisocyanide) complex of diazaporphyrin showing a unique (d <sub>xy</sub>)<sup>2</sup>(d<sub>xz</sub>, d<sub>yz</sub>)<sup>3</sup> ground state」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

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