抄録
Anion photoelectron spectroscopy was used to study small negatively charged vanadium oxide clusters at 4.66 eV photon energy. The electronic structure of the vanadium clusters was investigated as a function of size n and composition m. The changes of the electronic structure of the vanadium cluster cores after adding two oxygen atoms were examined. Thermomechanical cycles were used to determine relative dissociation energies for different oxygen-loss channels from the parent clusters. Electron affinities and vertical detachment energies were found to increase with increasing cluster size.
| 元の言語 | English |
|---|---|
| ページ（範囲） | 6521-6528 |
| ページ数 | 8 |
| ジャーナル | Journal of Chemical Physics |
| 巻 | 116 |
| 発行部数 | 15 |
| DOI | |
| 出版物ステータス | Published - 2002 4 15 |
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ASJC Scopus subject areas
- Atomic and Molecular Physics, and Optics
これを引用
Anion photoelectron spectroscopy of VnOm- (n=4-15; m=0-2). / Pramann, Axel; Koyasu, Kiichirou; Nakajima, Atsushi; Kaya, Koji.
：: Journal of Chemical Physics, 巻 116, 番号 15, 15.04.2002, p. 6521-6528.研究成果: Article
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TY - JOUR
T1 - Anion photoelectron spectroscopy of VnOm- (n=4-15; m=0-2)
AU - Pramann, Axel
AU - Koyasu, Kiichirou
AU - Nakajima, Atsushi
AU - Kaya, Koji
PY - 2002/4/15
Y1 - 2002/4/15
N2 - Anion photoelectron spectroscopy was used to study small negatively charged vanadium oxide clusters at 4.66 eV photon energy. The electronic structure of the vanadium clusters was investigated as a function of size n and composition m. The changes of the electronic structure of the vanadium cluster cores after adding two oxygen atoms were examined. Thermomechanical cycles were used to determine relative dissociation energies for different oxygen-loss channels from the parent clusters. Electron affinities and vertical detachment energies were found to increase with increasing cluster size.
AB - Anion photoelectron spectroscopy was used to study small negatively charged vanadium oxide clusters at 4.66 eV photon energy. The electronic structure of the vanadium clusters was investigated as a function of size n and composition m. The changes of the electronic structure of the vanadium cluster cores after adding two oxygen atoms were examined. Thermomechanical cycles were used to determine relative dissociation energies for different oxygen-loss channels from the parent clusters. Electron affinities and vertical detachment energies were found to increase with increasing cluster size.
UR - http://www.scopus.com/inward/record.url?scp=0037091137&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0037091137&partnerID=8YFLogxK
U2 - 10.1063/1.1461824
DO - 10.1063/1.1461824
M3 - Article
AN - SCOPUS:0037091137
VL - 116
SP - 6521
EP - 6528
JO - Journal of Chemical Physics
JF - Journal of Chemical Physics
SN - 0021-9606
IS - 15
ER -