Anion photoelectron spectroscopy of VnOm- (n=4-15; m=0-2)

Axel Pramann, Kiichirou Koyasu, Atsushi Nakajima, Koji Kaya

研究成果: Article査読

39 被引用数 (Scopus)

抄録

Anion photoelectron spectroscopy was used to study small negatively charged vanadium oxide clusters at 4.66 eV photon energy. The electronic structure of the vanadium clusters was investigated as a function of size n and composition m. The changes of the electronic structure of the vanadium cluster cores after adding two oxygen atoms were examined. Thermomechanical cycles were used to determine relative dissociation energies for different oxygen-loss channels from the parent clusters. Electron affinities and vertical detachment energies were found to increase with increasing cluster size.

本文言語English
ページ(範囲)6521-6528
ページ数8
ジャーナルJournal of Chemical Physics
116
15
DOI
出版ステータスPublished - 2002 4月 15

ASJC Scopus subject areas

  • 物理学および天文学(全般)
  • 物理化学および理論化学

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