Anti-Markovnikov Addition of Anilines to Aliphatic Terminal Alkynes Catalyzed by an 8-Quinolinolato Rhodium Complex

Yoshihiko Morimoto, Takuya Kochi, Fumitoshi Kakiuchi

研究成果: Article査読

抄録

Anti-Markovnikov addition of anilines to aliphatic terminal alkynes proceeded using an 8-quinolinolato rhodium/phosphine catalyst system. The use of a strong organic base, 1,1,3,3,–tetramethylguanidine, in the catalyst system enabled the formation of the aldimine products. Substrates with various functional groups including polar groups such as a phenolic hydroxy group are applicable to the hydroamination.

本文言語English
論文番号e2100125
ジャーナルHelvetica Chimica Acta
104
10
DOI
出版ステータスPublished - 2021 10

ASJC Scopus subject areas

  • 触媒
  • 生化学
  • 創薬
  • 物理化学および理論化学
  • 有機化学
  • 無機化学

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