抄録
Three ulose catalysts (1-3) were prepared from D-glucose via an intramolecular nitrile oxide cycloaddition (INOC) as the key step. The enantioselectivity of ulose 2 and 3 in asymmetric epoxidation was poor (up to 26% ee). Ulose 1 afforded good chemical yields (up to 83% yield) and the enantiomeric excess is up to 71% for the formation of (-)-trans-stilbene oxide.
| 本文言語 | English |
|---|---|
| ページ（範囲） | 7545-7552 |
| ページ数 | 8 |
| ジャーナル | Tetrahedron |
| 巻 | 58 |
| 号 | 37 |
| DOI | |
| 出版ステータス | Published - 2002 9月 9 |
ASJC Scopus subject areas
- 生化学
- 創薬
- 有機化学