Bimolecular solid-state photoreactions in the adduct crystals of an aromatic nitro compound with an aromatic amine

Yoshikatsu Ito, Sadayuki Asaoka, Isao Saito, Shigeru Ohba

研究成果: Article査読

10 被引用数 (Scopus)

抄録

Solid-state as well as solution-state photochemistry of the donor-acceptor complexes derived from an aromatic amine and an aromatic nitro compound was investigated. Of the twelve adduct crystals studied, only three involving m-DNB as the acceptor (9-MC/m-DNB, 9-EC/m-DNB and DMAP/m-DNB) were found to be photoreactive in the solid state, producing photoredox products probably through hydrogen abstraction by the excited nitro group. The FT-IR study has implicated that the NO2 group of m-DNB may be interacting with the donor's amino group in the crystalline state.

本文言語English
ページ(範囲)8193-8196
ページ数4
ジャーナルTetrahedron Letters
35
44
DOI
出版ステータスPublished - 1994 10 31

ASJC Scopus subject areas

  • 生化学
  • 創薬
  • 有機化学

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