Bimolecular solid-state photoreactions in the adduct crystals of an aromatic nitro compound with an aromatic amine

Yoshikatsu Ito, Sadayuki Asaoka, Isao Saito, Shigeru Ohba

研究成果: Article

10 引用 (Scopus)

抄録

Solid-state as well as solution-state photochemistry of the donor-acceptor complexes derived from an aromatic amine and an aromatic nitro compound was investigated. Of the twelve adduct crystals studied, only three involving m-DNB as the acceptor (9-MC/m-DNB, 9-EC/m-DNB and DMAP/m-DNB) were found to be photoreactive in the solid state, producing photoredox products probably through hydrogen abstraction by the excited nitro group. The FT-IR study has implicated that the NO2 group of m-DNB may be interacting with the donor's amino group in the crystalline state.

元の言語English
ページ(範囲)8193-8196
ページ数4
ジャーナルTetrahedron Letters
35
発行部数44
DOI
出版物ステータスPublished - 1994 10 31

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Nitro Compounds
Photochemistry
Amines
Hydrogen
Crystals
Photochemical reactions
Crystalline materials

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry
  • Drug Discovery

これを引用

Bimolecular solid-state photoreactions in the adduct crystals of an aromatic nitro compound with an aromatic amine. / Ito, Yoshikatsu; Asaoka, Sadayuki; Saito, Isao; Ohba, Shigeru.

:: Tetrahedron Letters, 巻 35, 番号 44, 31.10.1994, p. 8193-8196.

研究成果: Article

Ito, Yoshikatsu ; Asaoka, Sadayuki ; Saito, Isao ; Ohba, Shigeru. / Bimolecular solid-state photoreactions in the adduct crystals of an aromatic nitro compound with an aromatic amine. :: Tetrahedron Letters. 1994 ; 巻 35, 番号 44. pp. 8193-8196.
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