Biochemical preparations of both the enantiomers of methyl 3-hydroxypentanoate and their conversion to the enantiomers of 4-hexanolide, the pheromone of trogoderma glabrum1 1 This paper forms part 6 of the series. Preparative Bioorganic Chemistry, Part 5, T. Sugai and K. Mori, Agric. Biol. Chem. 48,2501 (1984).

Kenji Mori, Hideto Mori, Takeshi Sugai

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Title full: Biochemical preparations of both the enantiomers of methyl 3-hydroxypentanoate and their conversion to the enantiomers of 4-hexanolide, the pheromone of trogoderma glabrum1 1 This paper forms part 6 of the series. Preparative Bioorganic Chemistry, Part 5, T. Sugai and K. Mori, Agric. Biol. Chem. 48,2501 (1984). The experimental part of this work was taken from the B.Sc. Thesis of H.M. (March, 1984). This work was presented as a part of K.M.'s lecture at the Second Japan-Korea Seminar on Organic Chemistry (Kyoto, May 30,1984). Both the enantiomers of methyl 3-hydroxypentanoate were prepared by microbial asymmetric reduction of 3-oxopentanoic esters. Conversion of methyl 3-hydroxypentanoate to 4-hexanolide, the pheromone of Trogoderma glabrum, was achieved.

元の言語English
ページ(範囲)919-925
ページ数7
ジャーナルTetrahedron
41
発行部数5
DOI
出版物ステータスPublished - 1985
外部発表Yes

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ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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