Bis(N,N-dimethylethylenediamine-k2N,N′)-bis(perchlorato- kO)copper(II)

Takashiro Akitsu, Yasuaki Einaga

研究成果: Article

11 引用 (Scopus)

抄録

In the title compound, [Cu(ClO4)2(C4H 12N2)2], the Cu atom is located at a center of symmetry. It adopts an elongated octahedral trans-[CuN4O2] coordination geometry, which is a typical feature of the pseudo-Jahn-Teller effect. The axial Cu-O bond length is 2.605 (4) Å, while the in-plane Cu-N bond lengths are 1.987 (2) and 2.098 (2) Å.

元の言語English
ジャーナルActa Crystallographica Section E: Structure Reports Online
60
発行部数2
DOI
出版物ステータスPublished - 2004 2

Fingerprint

Jahn-Teller effect
Bond length
Copper
copper
symmetry
geometry
atoms
Atoms
Geometry
dimethylethylenediamine
perchlorate

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Structural Biology

これを引用

@article{ba54e99530914f76af1d5f5ed594b335,
title = "Bis(N,N-dimethylethylenediamine-k2N,N′)-bis(perchlorato- kO)copper(II)",
abstract = "In the title compound, [Cu(ClO4)2(C4H 12N2)2], the Cu atom is located at a center of symmetry. It adopts an elongated octahedral trans-[CuN4O2] coordination geometry, which is a typical feature of the pseudo-Jahn-Teller effect. The axial Cu-O bond length is 2.605 (4) {\AA}, while the in-plane Cu-N bond lengths are 1.987 (2) and 2.098 (2) {\AA}.",
author = "Takashiro Akitsu and Yasuaki Einaga",
year = "2004",
month = "2",
doi = "10.1107/S1600536804001461",
language = "English",
volume = "60",
journal = "Acta Crystallographica Section E: Structure Reports Online",
issn = "1600-5368",
publisher = "International Union of Crystallography",
number = "2",

}

TY - JOUR

T1 - Bis(N,N-dimethylethylenediamine-k2N,N′)-bis(perchlorato- kO)copper(II)

AU - Akitsu, Takashiro

AU - Einaga, Yasuaki

PY - 2004/2

Y1 - 2004/2

N2 - In the title compound, [Cu(ClO4)2(C4H 12N2)2], the Cu atom is located at a center of symmetry. It adopts an elongated octahedral trans-[CuN4O2] coordination geometry, which is a typical feature of the pseudo-Jahn-Teller effect. The axial Cu-O bond length is 2.605 (4) Å, while the in-plane Cu-N bond lengths are 1.987 (2) and 2.098 (2) Å.

AB - In the title compound, [Cu(ClO4)2(C4H 12N2)2], the Cu atom is located at a center of symmetry. It adopts an elongated octahedral trans-[CuN4O2] coordination geometry, which is a typical feature of the pseudo-Jahn-Teller effect. The axial Cu-O bond length is 2.605 (4) Å, while the in-plane Cu-N bond lengths are 1.987 (2) and 2.098 (2) Å.

UR - http://www.scopus.com/inward/record.url?scp=2442469485&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=2442469485&partnerID=8YFLogxK

U2 - 10.1107/S1600536804001461

DO - 10.1107/S1600536804001461

M3 - Article

AN - SCOPUS:2442469485

VL - 60

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

SN - 1600-5368

IS - 2

ER -