Bis(tetrahydrofuran)(2,7,12,17-tetrapropylporphycenato)iron(III) perchlorate: A pure intermediate spin complex

T. Ikeue, Y. Ohgo, M. Takahashi, M. Takeda, S. Neya, N. Funasaki, M. Nakamura

研究成果: Article査読

16 被引用数 (Scopus)

抄録

Combined analysis of bis(tetrahydrofuran)(2,7,12,17-tetrapropylporphycenato)iron(III) perchlorate, [Fe-(TPrPc)(THF)2]ClO4, using 1H NMR, EPR, and Mössbauer spectroscopy, as well as SQUID magnetometry, has revealed that the ferric ion of this complex is in a quite pure intermediate spin (S = 3/2) state. The result has been ascribed to the smaller cavity to accommodate the iron(III) ion as compared with the isomeric porphyrin complex.

本文言語English
ページ(範囲)3650-3652
ページ数3
ジャーナルInorganic Chemistry
40
14
DOI
出版ステータスPublished - 2001 7 2

ASJC Scopus subject areas

  • 物理化学および理論化学
  • 無機化学

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