TY - JOUR
T1 - (Bi1/2K1/2)TiO3–SrTiO3 solid-solution ceramics for high-temperature capacitor applications
AU - Shiga, Minami
AU - Hagiwara, Manabu
AU - Fujihara, Shinobu
N1 - Funding Information:
This work was supported by a Grant-in-Aid for Young Scientists (B) (No. 16K18241 ) from the Japan Society for the Promotion of Science (JSPS) .
Publisher Copyright:
© 2020 Elsevier Ltd and Techna Group S.r.l.
PY - 2020/6/1
Y1 - 2020/6/1
N2 - The relaxor state of (Bi1/2K1/2)TiO3 exhibits promising dielectric properties for high-temperature capacitor applications, but the spontaneous phase transition into the low-temperature ferroelectric state and the excessively high dielectric maximum temperature (Tm) at around 360 °C are the main drawback to this material. In this study we examined solid solutions of (Bi1/2K1/2)TiO3 with SrTiO3 to improve the temperature stability of the dielectric properties. As precursors to fabricate the sold-solution ceramics, fine powders of (Bi1/2K1/2)TiO3 and SrTiO3 were both synthesized by the hydrothermal method. Dense (1 − x)(Bi1/2K1/2)TiO3–xSrTiO3 ceramics with x up to 0.5 were then obtained by reaction sintering of the powders. A crystal structure analysis revealed that the average symmetry of the solid-solution ceramics changes from tetragonal to cubic with increasing the SrTiO3 content. Dielectric measurements showed that the incorporation of SrTiO3 into (Bi1/2K1/2)TiO3 stabilizes the relaxor state to shift Tm largely toward lower temperatures. As a result, the sample with x = 0.5 exhibited a temperature-stable dielectric permittivity of 1700 ± 15% over a wide temperature range from room temperature up to 260 °C. The electric-field and temperature dependences of the energy-storage properties of the sample were also investigated.
AB - The relaxor state of (Bi1/2K1/2)TiO3 exhibits promising dielectric properties for high-temperature capacitor applications, but the spontaneous phase transition into the low-temperature ferroelectric state and the excessively high dielectric maximum temperature (Tm) at around 360 °C are the main drawback to this material. In this study we examined solid solutions of (Bi1/2K1/2)TiO3 with SrTiO3 to improve the temperature stability of the dielectric properties. As precursors to fabricate the sold-solution ceramics, fine powders of (Bi1/2K1/2)TiO3 and SrTiO3 were both synthesized by the hydrothermal method. Dense (1 − x)(Bi1/2K1/2)TiO3–xSrTiO3 ceramics with x up to 0.5 were then obtained by reaction sintering of the powders. A crystal structure analysis revealed that the average symmetry of the solid-solution ceramics changes from tetragonal to cubic with increasing the SrTiO3 content. Dielectric measurements showed that the incorporation of SrTiO3 into (Bi1/2K1/2)TiO3 stabilizes the relaxor state to shift Tm largely toward lower temperatures. As a result, the sample with x = 0.5 exhibited a temperature-stable dielectric permittivity of 1700 ± 15% over a wide temperature range from room temperature up to 260 °C. The electric-field and temperature dependences of the energy-storage properties of the sample were also investigated.
KW - Capacitors
KW - Dielectric properties
KW - Lead-free relaxors
KW - Powders: chemical preparation
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U2 - 10.1016/j.ceramint.2020.01.016
DO - 10.1016/j.ceramint.2020.01.016
M3 - Article
AN - SCOPUS:85077715555
VL - 46
SP - 10242
EP - 10249
JO - Ceramics International
JF - Ceramics International
SN - 0272-8842
IS - 8
ER -