C-C bond formation with carbon dioxide promoted by a silver catalyst

Satoshi Kikuchi; Kohei Sekine; Tomonobu Ishida; Tohru Yamada

doi:10.1002/anie.201201399

C-C bond formation with carbon dioxide promoted by a silver catalyst

Satoshi Kikuchi, Kohei Sekine, Tomonobu Ishida, Tohru Yamada

化学科

研究成果: Article › 査読

85 被引用数 (Scopus)

抄録

A catalytic amount of silver benzoate with 7-methyl-1,5,7-triazabicyclo[4. 4.0]dec-5-ene (MTBD) was an effective catalytic system for the reaction of carbon dioxide with various ketones containing an alkyne group at an appropriate position (see scheme). These reactions afforded the corresponding γ-lactone derivatives in good to high yields under mild conditions.

本文言語	English
ページ（範囲）	6989-6992
ページ数	4
ジャーナル	Angewandte Chemie - International Edition
巻	51
号	28
DOI	https://doi.org/10.1002/anie.201201399
出版ステータス	Published - 2012 7月 9

ASJC Scopus subject areas

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化学 (全般)

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10.1002/anie.201201399

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abstract = "A catalytic amount of silver benzoate with 7-methyl-1,5,7-triazabicyclo[4. 4.0]dec-5-ene (MTBD) was an effective catalytic system for the reaction of carbon dioxide with various ketones containing an alkyne group at an appropriate position (see scheme). These reactions afforded the corresponding γ-lactone derivatives in good to high yields under mild conditions.",

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AU - Kikuchi, Satoshi

AU - Sekine, Kohei

AU - Ishida, Tomonobu

AU - Yamada, Tohru

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Y1 - 2012/7/9

N2 - A catalytic amount of silver benzoate with 7-methyl-1,5,7-triazabicyclo[4. 4.0]dec-5-ene (MTBD) was an effective catalytic system for the reaction of carbon dioxide with various ketones containing an alkyne group at an appropriate position (see scheme). These reactions afforded the corresponding γ-lactone derivatives in good to high yields under mild conditions.

AB - A catalytic amount of silver benzoate with 7-methyl-1,5,7-triazabicyclo[4. 4.0]dec-5-ene (MTBD) was an effective catalytic system for the reaction of carbon dioxide with various ketones containing an alkyne group at an appropriate position (see scheme). These reactions afforded the corresponding γ-lactone derivatives in good to high yields under mild conditions.

KW - C-C bond formation

KW - carbon dioxide

KW - homogeneous catalysis

KW - silver

KW - synthetic methods

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

SN - 1433-7851

IS - 28

ER -

C-C bond formation with carbon dioxide promoted by a silver catalyst

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