Carbon–Carbon Bond Formation via Catalytically Generated Aminocarbene Complexes: Rhodium-Catalyzed Hydroaminative Cyclization of Enynes with Secondary Amines

Shotaro Takano, Ryosuke Shiomi, Yoshihiko Morimoto, Takuya Kochi, Fumitoshi Kakiuchi

研究成果: Article査読

抄録

We report a hydroaminative cyclization of enynes using phosphine-quinolinolato rhodium catalysts. The hydroaminative cyclization of 2-vinylphenylacetylene derivatives with secondary amines gives 2-aminoindenes in good yields. The reaction is considered to proceed through carbon–carbon bond formation on a catalytically generated aminocarbene ligand.

本文言語English
ページ(範囲)11754-11757
ページ数4
ジャーナルAngewandte Chemie - International Edition
59
29
DOI
出版ステータスPublished - 2020 7 13

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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