TY - JOUR
T1 - Catalysis by Hydrotalcite in Liquid-phase Organic Reactions
AU - Ono, Y.
AU - Suzuki, E.
AU - Okamoto, M.
PY - 1991/1/1
Y1 - 1991/1/1
N2 - The interlayer Cl− anions in a synthetic hydrotalcite-like material, Mg6Al2(OH)16Cl2.4H2O, were found to react with organic bromides in a non-polar solvent of toluene, almost all chloride ions in the interlayer space appearing in the liquid phase as the corresponding organic chlorides. The hydrotalcite-like material was found to catalyze organic reactions in which the interlayer Cl− anions play the role of catalyst. Thus, the material catalyzed the halide-exchange reactions between alkyl halides in toluene and the disproportionation of trimethoxysilane to give silane and tetramethoxysilane.
AB - The interlayer Cl− anions in a synthetic hydrotalcite-like material, Mg6Al2(OH)16Cl2.4H2O, were found to react with organic bromides in a non-polar solvent of toluene, almost all chloride ions in the interlayer space appearing in the liquid phase as the corresponding organic chlorides. The hydrotalcite-like material was found to catalyze organic reactions in which the interlayer Cl− anions play the role of catalyst. Thus, the material catalyzed the halide-exchange reactions between alkyl halides in toluene and the disproportionation of trimethoxysilane to give silane and tetramethoxysilane.
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U2 - 10.1016/S0167-2991(08)61914-X
DO - 10.1016/S0167-2991(08)61914-X
M3 - Article
AN - SCOPUS:0041715389
VL - 60
SP - 363
EP - 370
JO - Studies in Surface Science and Catalysis
JF - Studies in Surface Science and Catalysis
SN - 0167-2991
IS - C
ER -