抄録
The interlayer Cl− anions in a synthetic hydrotalcite-like material, Mg6Al2(OH)16Cl2.4H2O, were found to react with organic bromides in a non-polar solvent of toluene, almost all chloride ions in the interlayer space appearing in the liquid phase as the corresponding organic chlorides. The hydrotalcite-like material was found to catalyze organic reactions in which the interlayer Cl− anions play the role of catalyst. Thus, the material catalyzed the halide-exchange reactions between alkyl halides in toluene and the disproportionation of trimethoxysilane to give silane and tetramethoxysilane.
本文言語 | English |
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ページ(範囲) | 363-370 |
ページ数 | 8 |
ジャーナル | Studies in Surface Science and Catalysis |
巻 | 60 |
号 | C |
DOI | |
出版ステータス | Published - 1991 1 1 |
外部発表 | はい |
ASJC Scopus subject areas
- Catalysis
- Condensed Matter Physics
- Physical and Theoretical Chemistry
- Surfaces, Coatings and Films
- Materials Chemistry