Catalysis by Hydrotalcite in Liquid-phase Organic Reactions

Y. Ono, E. Suzuki, M. Okamoto

研究成果: Article査読

3 被引用数 (Scopus)

抄録

The interlayer Cl anions in a synthetic hydrotalcite-like material, Mg6Al2(OH)16Cl2.4H2O, were found to react with organic bromides in a non-polar solvent of toluene, almost all chloride ions in the interlayer space appearing in the liquid phase as the corresponding organic chlorides. The hydrotalcite-like material was found to catalyze organic reactions in which the interlayer Cl anions play the role of catalyst. Thus, the material catalyzed the halide-exchange reactions between alkyl halides in toluene and the disproportionation of trimethoxysilane to give silane and tetramethoxysilane.

本文言語English
ページ(範囲)363-370
ページ数8
ジャーナルStudies in Surface Science and Catalysis
60
C
DOI
出版ステータスPublished - 1991 1 1
外部発表はい

ASJC Scopus subject areas

  • Catalysis
  • Condensed Matter Physics
  • Physical and Theoretical Chemistry
  • Surfaces, Coatings and Films
  • Materials Chemistry

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