Catalytic addition of C-H bonds to multiple bonds with the aid of ruthenium complexes

Shinji Murai, Naoto Chatani, Fumitoshi Kakiuchi

研究成果: Article査読

2 被引用数 (Scopus)

抄録

Ruthenium complexes, e.g., RuH2(CO)(PPh3)3, have been found to catalyze the direct addition of ortho carbon-hydrogen bonds of aromatic ketones to olefins and acetylenes with high efficiency and selectivity. The C-H/olefin coupling reaction is applicable to not only C-H bonds in aromatic ketones but also to those in α,β-enones and aromatic esters. Catalytic addition of ortho carbon-hydrogen bonds of aromatic imines to olefins is found to be catalyzed by Ru3(CO)12.

本文言語English
ページ(範囲)35-51
ページ数17
ジャーナルCatalysis Surveys from Japan
1
1
DOI
出版ステータスPublished - 1997 1月 1
外部発表はい

ASJC Scopus subject areas

  • 触媒
  • 物理化学および理論化学

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