TY - JOUR
T1 - Catalytic asymmetric fluorination using CSF sparingly soluble in organic solvent
AU - Tsutsumi, Ryosuke
N1 - Publisher Copyright:
© 2020 Society of Synthetic Organic Chemistry. All rights reserved.
PY - 2020
Y1 - 2020
N2 - Metal fluorides such as KF and CsF are inexpensive and easy-to-handle nucleophilic fluorinating reagents while their insolubility in most organic solvents often causes a problem in their synthetic use. In this review, examples of nucleophilic fluorination promoted by a hydrogen-bonding donor are described. Moreover, a recent research on asymmetric nucleophilic fluorination using a chiral hydrogen-bond donor catalyst is introduced.
AB - Metal fluorides such as KF and CsF are inexpensive and easy-to-handle nucleophilic fluorinating reagents while their insolubility in most organic solvents often causes a problem in their synthetic use. In this review, examples of nucleophilic fluorination promoted by a hydrogen-bonding donor are described. Moreover, a recent research on asymmetric nucleophilic fluorination using a chiral hydrogen-bond donor catalyst is introduced.
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U2 - 10.5059/yukigoseikyokaishi.78.158
DO - 10.5059/yukigoseikyokaishi.78.158
M3 - Review article
AN - SCOPUS:85084341020
VL - 78
SP - 158
EP - 159
JO - Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry
JF - Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry
SN - 0037-9980
IS - 2
ER -