抄録
(Chemical Equation Presented) The atropo-enantioselective borohydride reduction with dynamic kinetic resolution of biaryl lactones was catalyzed by an optically active β-ketoiminatocobalt(II) complex to afford optically active biaryl compounds. Chiral HPLC analysis of the starting biaryl lactones was performed at various temperatures to determine suitable reaction conditions for dynamic kinetic resolution. Various types of axially chiral biaryl compounds were obtained with high enantioselectivity.
| 本文言語 | English |
|---|---|
| ページ（範囲） | 2521-2524 |
| ページ数 | 4 |
| ジャーナル | Organic Letters |
| 巻 | 10 |
| 号 | 12 |
| DOI | |
| 出版ステータス | Published - 2008 12 1 |
ASJC Scopus subject areas
- 生化学
- 物理化学および理論化学
- 有機化学