Catalytic C-H/olefin coupling

Fumitoshi Kakiuchi, Shinji Murai

研究成果: Article査読

994 被引用数 (Scopus)

抄録

The cleavage and addition of ortho C-H bonds in various aromatic compounds such as ketones, esters, imines, imidates, nitrile, and aldehydes to olefins and acetlylenes can be achieved catalytically with the aid of ruthenium catalysts. The reaction is generally highly efficient and useful in synthetic methods. The coordination to the metal center by a heteroatom in directing groups such as carbonyl and imino groups is the key. The reductive elimination to form a C-C bond is the rate-determining step.

本文言語English
ページ(範囲)826-834
ページ数9
ジャーナルAccounts of Chemical Research
35
10
DOI
出版ステータスPublished - 2002 10月
外部発表はい

ASJC Scopus subject areas

  • 化学 (全般)

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