Catalytic C-H/olefin coupling

Shinji Mural, Fumitoshi Kakiuchi, Shinya Sekine, Yasuo Tanaka, Asayuki Kamatani, Motohiro Sonoda, Naoto Chatani

研究成果: Article査読

110 被引用数 (Scopus)

抄録

Several ruthenium complexes have been found to catalyze the addition of the C-H bond of arenes to olefins. Phenyl methyl ketone undergoes addition at its ortho position across the double bond of trimethylvinylsilane in the presence of a catalytic amount of RuH2(CO)(PPh3)3 to give 1 : 1 and 1 : 2 coupling products. In the latter, the two ortho hydrogens have reacted. Similarly, 2-methylphenyl methyl ketone reacts with trimethylvinylsilane and triethoxyvinylsilane to give the corresponding 1 : 1 coupling products in virtually quantitative yields. The results represent a breakthrough in the chemistry of carbon-hydrogen bond cleavage by metal complexes.

本文言語English
ページ(範囲)1527-1534
ページ数8
ジャーナルPure and Applied Chemistry
66
7
DOI
出版ステータスPublished - 1994 1 1
外部発表はい

ASJC Scopus subject areas

  • Chemistry(all)
  • Chemical Engineering(all)

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