Catalytic, Directed C-C Bond Functionalization of Styrenes

Shunsuke Onodera, Ryo Togashi, Soya Ishikawa, Takuya Kochi, Fumitoshi Kakiuchi

研究成果: Article査読

12 被引用数 (Scopus)

抄録

A method for catalytic conversion of C(aryl)-C(alkenyl) bonds in styrene derivatives to new C-C bonds is developed. In the presence of a rhodium catalyst, the alkenyl groups of styrenes bearing a pyrazolyl directing group were efficiently converted to other carbon substituents upon reacting with various alkenes including styrenes, aliphatic alkenes, and allyl alcohols. It is also indicated that the C-C bond cleavage proceeded via a hydrometalation/β-carbon elimination pathway.

本文言語English
ページ(範囲)7345-7349
ページ数5
ジャーナルJournal of the American Chemical Society
142
16
DOI
出版ステータスPublished - 2020 4月 22

ASJC Scopus subject areas

  • 触媒
  • 化学 (全般)
  • 生化学
  • コロイド化学および表面化学

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