Catalytic electrochemical C-H iodination and one-pot arylation by ON/OFF switching of electric current

Hiroko Aiso, Takuya Kochi, Hitoshi Mutsutani, Takamasa Tanabe, Shigeru Nishiyama, Fumitoshi Kakiuchi

研究成果: Article査読

89 被引用数 (Scopus)

抄録

Palladium-catalyzed electrochemical iodination and one-pot arylation of arylpyridines are described. Ortho-selective C-H iodination proceeded via dual activation of each substrate by a palladium catalyst and an electrode. Various aryl groups were introduced at the ortho positions of arylpyridines by ON/OFF switching of two different catalytic cycles using the same palladium catalyst in a one-pot fashion.

本文言語English
ページ(範囲)7718-7724
ページ数7
ジャーナルJournal of Organic Chemistry
77
17
DOI
出版ステータスPublished - 2012 9月 7

ASJC Scopus subject areas

  • 有機化学

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