Catalytic enantioselective protonation of cobalt-enolate equivalents generated by 1,4-reduction with borohydride

Yuhki Ohtsuka, Taketo Ikeno, Tohru Yamada

研究成果: Article査読

43 被引用数 (Scopus)

抄録

In the presence of a catalytic amount of the optically active β-ketoiminato cobalt(II) complex and borohydride modified with appropriate alcohols, the 1,4-reduction of α-substituted-α,β-unsaturated carboxamides followed by in situ enantioselective protonation proceeded smoothly to afford optically active α-substituted carboxamides with good enantiomeric excess.

本文言語English
ページ(範囲)967-970
ページ数4
ジャーナルTetrahedron Asymmetry
14
8
DOI
出版ステータスPublished - 2003 4 18

ASJC Scopus subject areas

  • Catalysis
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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