Catalytic oxidation-reduction hydration of olefin with molecular oxygen in the presence of bis(1,3-diketonato)cobalt(II) complexes

K. Kato, T. Yamada, T. Takai, S. Inoki, S. Isayama

研究成果: Article査読

76 被引用数 (Scopus)

抄録

In the presence of a bis(1,3-diketonato)cobalt(II) complex, various olefins are converted to the corresponding hydrated products according to the Markownikov rule on treatment with molecular oxygen in secondary alcohol (''oxidation-reduction hydration''). Removal of water formed during the hydration reaction, especially by azeotropic method, is remarkably effective to improve yields of the hydrated products based on the cobalt(II) catalyst as bis(trifluoroacetylacetonato)cobalt(II) (Co(tfa)2) or bis(2-ethoxycarbonyl-3-oxobutanalato)-cobalt(II) (Co(ecbo)2).

本文言語English
ページ(範囲)179-186
ページ数8
ジャーナルBulletin of the Chemical Society of Japan
63
1
DOI
出版ステータスPublished - 1990 6月 22
外部発表はい

ASJC Scopus subject areas

  • 化学 (全般)

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