Catena-Poly[[tetrakis(μ-3,3-dimethyl-butyrato-O:O′)dicopper(II)]- μ-3,3-di-methylbutyrato-O:O′-[bis(2,6-di-methylpyridine-N)copper(ll)]- μ-3,3-dimethylbutyrato-O:O′] and tetrakis-(μ-2,2-dimethylpropanoato-O:O′)bis-[(2,6-dimethyIpyridine-N) copper(ll)]

Yoshiyuki Kani; Masanobu Tsuchimoto; Shigeru Ohba; Hideaki Matsushima; Tadashi Tokii

doi:10.1107/S0108270100006697

Catena-Poly[[tetrakis(μ-3,3-dimethyl-butyrato-O:O′)dicopper(II)]- μ-3,3-di-methylbutyrato-O:O′-[bis(2,6-di-methylpyridine-N)copper(ll)]- μ-3,3-dimethylbutyrato-O:O′] and tetrakis-(μ-2,2-dimethylpropanoato-O:O′)bis-[(2,6-dimethyIpyridine-N) copper(ll)]

Yoshiyuki Kani, Masanobu Tsuchimoto, Shigeru Ohba, Hideaki Matsushima, Tadashi Tokii

研究成果: Article › 査読

10 被引用数 (Scopus)

抄録

The two title compounds, [Cu₃(C₆H₁₁O₂)₆(C ₇H₉N)₂]_n, (I), and [Cu₂(C₅H₉O₂)₄(C ₇H₉N)₂], (II), have chain and finite-molecular structures, respectively. In (I), binuclear cage units and mononuclear 2,6-dimethylpyridine complexes, both of which have inversion centres, are arranged alternately and are linked by the carboxylate ions to form one-dimensional chains along the a axis. In (II), the binuclear cage unit has an inversion centre and the coordination geometry around the Cu atom is typical square pyramidal, with 2,6-dimethylpyridine at the apical position.

本文言語	English
ページ（範囲）	923-925
ページ数	3
ジャーナル	Acta Crystallographica Section C: Crystal Structure Communications
巻	56
号	8
DOI	https://doi.org/10.1107/S0108270100006697
出版ステータス	Published - 2000
外部発表	はい

ASJC Scopus subject areas

生化学、遺伝学、分子生物学（全般）

文献へのアクセス

10.1107/S0108270100006697

他のファイルとリンク

フィンガープリント

「Catena-Poly[[tetrakis(μ-3,3-dimethyl-butyrato-O:O′)dicopper(II)]- μ-3,3-di-methylbutyrato-O:O′-[bis(2,6-di-methylpyridine-N)copper(ll)]- μ-3,3-dimethylbutyrato-O:O′] and tetrakis-(μ-2,2-dimethylpropanoato-O:O′)bis-[(2,6-dimethyIpyridine-N) copper(ll)]」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル

Kani, Y., Tsuchimoto, M., Ohba, S., Matsushima, H., & Tokii, T. (2000). Catena-Poly[[tetrakis(μ-3,3-dimethyl-butyrato-O:O′)dicopper(II)]- μ-3,3-di-methylbutyrato-O:O′-[bis(2,6-di-methylpyridine-N)copper(ll)]- μ-3,3-dimethylbutyrato-O:O′] and tetrakis-(μ-2,2-dimethylpropanoato-O:O′)bis-[(2,6-dimethyIpyridine-N) copper(ll)]. Acta Crystallographica Section C: Crystal Structure Communications, 56(8), 923-925. https://doi.org/10.1107/S0108270100006697

Catena-Poly[[tetrakis(μ-3,3-dimethyl-butyrato-O:O′)dicopper(II)]- μ-3,3-di-methylbutyrato-O:O′-[bis(2,6-di-methylpyridine-N)copper(ll)]- μ-3,3-dimethylbutyrato-O:O′] and tetrakis-(μ-2,2-dimethylpropanoato-O:O′)bis-[(2,6-dimethyIpyridine-N) copper(ll)]. / Kani, Yoshiyuki; Tsuchimoto, Masanobu; Ohba, Shigeru その他.
In: Acta Crystallographica Section C: Crystal Structure Communications, Vol. 56, No. 8, 2000, p. 923-925.

研究成果: Article › 査読

Kani, Y, Tsuchimoto, M, Ohba, S, Matsushima, H & Tokii, T 2000, 'Catena-Poly[[tetrakis(μ-3,3-dimethyl-butyrato-O:O′)dicopper(II)]- μ-3,3-di-methylbutyrato-O:O′-[bis(2,6-di-methylpyridine-N)copper(ll)]- μ-3,3-dimethylbutyrato-O:O′] and tetrakis-(μ-2,2-dimethylpropanoato-O:O′)bis-[(2,6-dimethyIpyridine-N) copper(ll)]', Acta Crystallographica Section C: Crystal Structure Communications, vol. 56, no. 8, pp. 923-925. https://doi.org/10.1107/S0108270100006697

Kani Y, Tsuchimoto M, Ohba S, Matsushima H, Tokii T. Catena-Poly[[tetrakis(μ-3,3-dimethyl-butyrato-O:O′)dicopper(II)]- μ-3,3-di-methylbutyrato-O:O′-[bis(2,6-di-methylpyridine-N)copper(ll)]- μ-3,3-dimethylbutyrato-O:O′] and tetrakis-(μ-2,2-dimethylpropanoato-O:O′)bis-[(2,6-dimethyIpyridine-N) copper(ll)]. Acta Crystallographica Section C: Crystal Structure Communications. 2000;56(8):923-925. doi: 10.1107/S0108270100006697

Kani, Yoshiyuki ; Tsuchimoto, Masanobu ; Ohba, Shigeru その他. / Catena-Poly[[tetrakis(μ-3,3-dimethyl-butyrato-O:O′)dicopper(II)]- μ-3,3-di-methylbutyrato-O:O′-[bis(2,6-di-methylpyridine-N)copper(ll)]- μ-3,3-dimethylbutyrato-O:O′] and tetrakis-(μ-2,2-dimethylpropanoato-O:O′)bis-[(2,6-dimethyIpyridine-N) copper(ll)]. In: Acta Crystallographica Section C: Crystal Structure Communications. 2000 ; Vol. 56, No. 8. pp. 923-925.

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title = "Catena-Poly[[tetrakis(μ-3,3-dimethyl-butyrato-O:O′)dicopper(II)]- μ-3,3-di-methylbutyrato-O:O′-[bis(2,6-di-methylpyridine-N)copper(ll)]- μ-3,3-dimethylbutyrato-O:O′] and tetrakis-(μ-2,2-dimethylpropanoato-O:O′)bis-[(2,6-dimethyIpyridine-N) copper(ll)]",

abstract = "The two title compounds, [Cu3(C6H11O2)6(C 7H9N)2]n, (I), and [Cu2(C5H9O2)4(C 7H9N)2], (II), have chain and finite-molecular structures, respectively. In (I), binuclear cage units and mononuclear 2,6-dimethylpyridine complexes, both of which have inversion centres, are arranged alternately and are linked by the carboxylate ions to form one-dimensional chains along the a axis. In (II), the binuclear cage unit has an inversion centre and the coordination geometry around the Cu atom is typical square pyramidal, with 2,6-dimethylpyridine at the apical position.",

author = "Yoshiyuki Kani and Masanobu Tsuchimoto and Shigeru Ohba and Hideaki Matsushima and Tadashi Tokii",

year = "2000",

doi = "10.1107/S0108270100006697",

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journal = "Acta Crystallographica Section C: Crystal Structure Communications",

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T1 - Catena-Poly[[tetrakis(μ-3,3-dimethyl-butyrato-O:O′)dicopper(II)]- μ-3,3-di-methylbutyrato-O:O′-[bis(2,6-di-methylpyridine-N)copper(ll)]- μ-3,3-dimethylbutyrato-O:O′] and tetrakis-(μ-2,2-dimethylpropanoato-O:O′)bis-[(2,6-dimethyIpyridine-N) copper(ll)]

AU - Kani, Yoshiyuki

AU - Tsuchimoto, Masanobu

AU - Ohba, Shigeru

AU - Matsushima, Hideaki

AU - Tokii, Tadashi

PY - 2000

Y1 - 2000

N2 - The two title compounds, [Cu3(C6H11O2)6(C 7H9N)2]n, (I), and [Cu2(C5H9O2)4(C 7H9N)2], (II), have chain and finite-molecular structures, respectively. In (I), binuclear cage units and mononuclear 2,6-dimethylpyridine complexes, both of which have inversion centres, are arranged alternately and are linked by the carboxylate ions to form one-dimensional chains along the a axis. In (II), the binuclear cage unit has an inversion centre and the coordination geometry around the Cu atom is typical square pyramidal, with 2,6-dimethylpyridine at the apical position.

AB - The two title compounds, [Cu3(C6H11O2)6(C 7H9N)2]n, (I), and [Cu2(C5H9O2)4(C 7H9N)2], (II), have chain and finite-molecular structures, respectively. In (I), binuclear cage units and mononuclear 2,6-dimethylpyridine complexes, both of which have inversion centres, are arranged alternately and are linked by the carboxylate ions to form one-dimensional chains along the a axis. In (II), the binuclear cage unit has an inversion centre and the coordination geometry around the Cu atom is typical square pyramidal, with 2,6-dimethylpyridine at the apical position.

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