Cathodic reductive coupling of methyl cinnamate on boron-doped diamond electrodes and synthesis of new neolignan-type products

Taiki Kojima, Rika Obata, Tsuyoshi Saito, Yasuaki Einaga, Shigeru Nishiyama

研究成果: Article査読

14 被引用数 (Scopus)

抄録

The electroreduction reaction of methyl cinnamate on a boron-doped diamond (BDD) electrode was investigated. The hydrodimer, dimethyl 3,4-diphenylhexanedioate (racemate/meso = 74:26), was obtained in 85% yield as the major product, along with small amounts of cyclic methyl 5-oxo-2,3-diphenylcyclopentane-1-carboxylate. Two new neolignan-type products were synthesized from the hydrodimer.

本文言語English
ページ(範囲)200-203
ページ数4
ジャーナルBeilstein Journal of Organic Chemistry
11
DOI
出版ステータスPublished - 2015 2 3

ASJC Scopus subject areas

  • 有機化学

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