Chemical studies on 2,4-dihydroxy-7-methoxy-2H-1,4-benzoxazin-3(4H)-one in connection with 6-methoxy-2-benzoxazolinone, an auxin-inhibiting substance of Zea mays L.

Seiji Kosemura, Shosuke Yamamura, Toyoaki Anai, Koji Hasegawa

研究成果: Article査読

18 被引用数 (Scopus)

抄録

Some chemical studies on 2,4-dihydroxy-7-methoxy-2H-1,4-benzoxazin-3(4H)-one (DIMBOA, 1) and related compounds from Zea mays L. have been carried out, where DIMBOA (1) has been very rapidly converted into 6-methoxy-2-benzoxazolinone (MBOA, 2), an auxin-inhibiting substanse of maize, in the presence of acetic anhydride at room temperature. Therefore, such an enzymatic acylation of N-OH group of DIMBOA (1) as in vitro presumably plays an important role on phototropism.

本文言語English
ページ(範囲)8221-8224
ページ数4
ジャーナルTetrahedron Letters
35
44
DOI
出版ステータスPublished - 1994 10月 31

ASJC Scopus subject areas

  • 生化学
  • 創薬
  • 有機化学

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「Chemical studies on 2,4-dihydroxy-7-methoxy-2H-1,4-benzoxazin-3(4H)-one in connection with 6-methoxy-2-benzoxazolinone, an auxin-inhibiting substance of Zea mays L.」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

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