Chemoselectivity-independent Cu-mediated coupling to construct the hydroquinoline skeleton of symbioimine

研究成果: Article査読

抄録

Construction of the hydroquinoline skeleton of symbioimine by Cu-mediated N-alkenylation or O-alkenylation of an allyl aminoalcohol, in which either chemoselectivity could lead to the target compound, was investigated. O-alkenylation followed by Claisen rearrangement was favored with high selectivity under a ligand-free condition. Subsequent intramolecular condensation furnished the hydroquinoline skeleton of symbioimine.

本文言語English
論文番号24078
ジャーナルScientific reports
11
1
DOI
出版ステータスPublished - 2021 12月

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