Chloroform is not solvent but activator for cobalt complex catalyst of enantioselective borohydride reduction

Ai Kokura, Saiko Tanaka, Haruna Teraoka, Atsushi Shibahrara, Taketo Ikeno, Takushi Nagata, Tohru Yamada

研究成果: Article査読

12 被引用数 (Scopus)

抄録

For the enantioselective borohydride reduction of carbonyl compounds catalyzed by the optically active ketoiminatocobalt complexes, chloroform has been employed as a unique solvent for achieving a high enantioselectivity, whereas it was found that a catalytic amount of chloroform effectively activated the present catalytic system to convert various ketones into the corresponding reduced product with a high ee in the THF solvent.

本文言語English
ページ(範囲)26-27
ページ数2
ジャーナルChemistry Letters
36
1
DOI
出版ステータスPublished - 2007 1月 5

ASJC Scopus subject areas

  • 化学 (全般)

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