Circular dichroism in a chiral amide possessing an achiral binaphthyl chromophore

Shinzo Hosoi, Jun Serata, Akiyo Sakushima, Fumiyuki Kiuchi, Ichiro Takahashi, Tomihisa Ohta

研究成果: Article

4 引用 (Scopus)

抜粋

Induced circular dichroism (ICD) was observed in binaphthyl amides of chiral primary amines. The CDs changed to split curves centered at 225 nm after N-methylation. The calculated screw senses of the two naphthyl groups accorded with those expected from their exciton chiralities, indicating a possible application for determination of absolute configuration.

元の言語English
ページ(範囲)58-61
ページ数4
ジャーナルLetters in Organic Chemistry
3
発行部数1
DOI
出版物ステータスPublished - 2006 1

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry

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