Coagel Prepared from Aqueous Octyl β -d-Galactoside Solution

Shigesaburo Ogawa, Maito Koga, Kouichi Asakura, Isao Takahashi, Shuichi Osanai

研究成果: Article査読

3 被引用数 (Scopus)

抄録

Structuring of semi-crystalline networks in water systems is significant for a variety of industrial applications. In the present work, we investigated the coagel formation from aqueous octyl β-d-galactoside (C8-β-Gal) solutions and characterized the crystal structure and crystallite network in the prepared coagel. Differential scanning calorimetry (DSC) confirmed that the Krafft boundary temperature (TK) is 32–35 °C for C8-β-Gal concentrations below 30 wt% and a knee of the Krafft boundary exists around 2.5 wt% C8-β-Gal concentrations. The addition of NaCl increased TK slightly because of the salting-out effect. Powder X-ray diffraction (PXRD) analysis, field-emission scanning electron microscopy (FE-SEM) and atomic force microscopy (AFM) observations revealed that the coagel is comprised of the three dimensional bundled semi-crystalline network consisting of a “ribbon crystal phase” of hemihydrate crystals. Moreover, the excellent ability of C8-β-Gal to form a macroscopically homogeneous coagel was demonstrated by the comparison with other representative mono-alkylated glycoside’ systems containing octyl a-d-glucoside or dodecyl β-d-glucoside. Persistence of the liquid phase without liquid–liquid phase separation prior to and during the coagel formation was a key factor for the preparation. A novel coagel was obtained from a principal synthetic galactoside.

本文言語English
ページ(範囲)255-261
ページ数7
ジャーナルJournal of Surfactants and Detergents
20
1
DOI
出版ステータスPublished - 2017 1 1

ASJC Scopus subject areas

  • 化学工学(全般)
  • 物理化学および理論化学
  • 表面、皮膜および薄膜

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