Cobalt-catalyzed oxidative kinetic resolution of secondary benzylic alcohols with molecular oxygen

Tohru Yamada, Sho Higano, Takanori Yano, Yoshihiro Yamashita

研究成果: Article査読

19 被引用数 (Scopus)

抄録

The oxidative kinetic resolution of secondary alcohols using molecular oxygen and olefins was catalyzed by the optically active ketoiminatocobalt(II) complexes. The various secondary benzylic alcohols were subjected to the aerobic oxidative reaction to afford optically active alcohols of high ee along with the corresponding ketones in high yield. The oxidation of the deuterated alcohols revealed that the accompanying olefin mediated the oxidation for conversion to the corresponding α-deuterated ketones.

本文言語English
ページ(範囲)40-41
ページ数2
ジャーナルChemistry Letters
38
1
DOI
出版ステータスPublished - 2009

ASJC Scopus subject areas

  • 化学 (全般)

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