Cobalt-catalyzed reductive carboxylation of α,β-unsaturated compounds with carbon dioxide

Chika Hayashi, Takuo Hayashi, Tohru Yamada

研究成果: Article査読

19 被引用数 (Scopus)

抄録

The gaseous carbon dioxide incorporation reaction with α,β-unsaturated compounds was examined in the presence of a catalytic amount of bis(acetylacetonato)cobalt(II) and using diethylzinc as a reductant. After screening with various electron-withdrawing groups, both α,β-unsaturated nitriles and carboxamides were found to efficiently capture carbon dioxide to provide the corresponding carboxylates or malonates in good to excellent yields under mild conditions.

本文言語English
ページ(範囲)862-870
ページ数9
ジャーナルBulletin of the Chemical Society of Japan
88
6
DOI
出版ステータスPublished - 2015

ASJC Scopus subject areas

  • 化学 (全般)

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